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{:(CHO),(|),((CHOH)),(|),(CH2OH):} under...

`{:(CHO),(|),((CHOH)),(|),(CH_2OH):} underset(Ca(OH)_2)overset(Br_2 ,H_2 O)to underset(Fe^(3+))overset(H_2 O_2)to ` Product :

A

`{:(COOH),(|),((CHOH)_3),(|),(CH_2OH):}`

B

`{:(CHO),(|),((CHOH)_4),(|),(CH_2OH):}`

C

`{:(CHO),(|),((CHOH)_2),(|),(CH_2OH):}`

D

`{:(COOH),(|),((CHOH)_3),(|),(COOH):}`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we will go through the reactions step by step, starting from the initial compound and applying the reagents in the order specified. ### Step 1: Identify the Initial Compound The initial compound is represented as `{:(CHO),(|),((CHOH)),(|),(CH_2OH):}`. This can be interpreted as: - One aldehyde group (CHO) - Two hydroxymethyl groups (CHOH) - One additional hydroxymethyl group (CH2OH) ### Step 2: Reaction with Bromine Water (Br2 + H2O) When the compound reacts with bromine water, the aldehyde group (CHO) is oxidized to a carboxylic acid (COOH). The reaction can be summarized as follows: - CHO → COOH Thus, the compound now looks like this: - COOH, CHOH, CHOH, CH2OH ### Step 3: Reaction with Calcium Hydroxide (Ca(OH)2) Calcium hydroxide acts as a base and can deprotonate the carboxylic acid, forming a calcium salt. The reaction can be represented as: - COOH + Ca(OH)2 → Ca(COO)2 + H2O This results in the formation of a calcium salt of the carboxylic acid, which can be represented as: - Ca(COO)2, CHOH, CHOH, CH2OH ### Step 4: Reaction with Hydrogen Peroxide (H2O2) and Iron (Fe3+) The next step involves the reaction with hydrogen peroxide in the presence of iron. Hydrogen peroxide can provide hydroxyl radicals, which can further oxidize the compound. The presence of Fe3+ can also facilitate the oxidation process. The hydroxyl groups will be introduced to the existing structure. After this reaction, we can expect the following transformation: - The compound retains its structure but may undergo further oxidation, leading to the formation of additional hydroxyl groups. ### Step 5: Elimination of Water During the reaction, if there are two hydroxyl groups on the same carbon, dehydration can occur, leading to the elimination of water. This will yield a compound with fewer hydroxyl groups. ### Step 6: Final Product After all the reactions, we summarize the final product: - The product will have a carboxylic acid group, hydroxymethyl groups, and possibly an aldehyde group depending on the extent of oxidation. ### Conclusion The final product can be represented as: - CHO (aldehyde), COOH (carboxylic acid), CHOH (hydroxymethyl), and CH2OH (hydroxymethyl). ### Matching with Options Now we compare the final product with the given options: - Option A: Incorrect due to the presence of too many carboxylic groups. - Option B: Incorrect due to the presence of too many hydroxymethyl groups. - Option C: Correct as it matches the expected structure. - Option D: Incorrect due to the presence of too many carboxylic groups. ### Final Answer The correct option is **C**.

To solve the given question, we will go through the reactions step by step, starting from the initial compound and applying the reagents in the order specified. ### Step 1: Identify the Initial Compound The initial compound is represented as `{:(CHO),(|),((CHOH)),(|),(CH_2OH):}`. This can be interpreted as: - One aldehyde group (CHO) - Two hydroxymethyl groups (CHOH) - One additional hydroxymethyl group (CH2OH) ...
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