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Which of the following aromatic compound...

Which of the following aromatic compounds will react with `KMnO_(4)` ?

A

B

C

D

Text Solution

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The correct Answer is:
To determine which aromatic compounds will react with KMnO4, we need to analyze the presence of alpha hydrogens in each compound. KMnO4 is a strong oxidizing agent that requires at least one alpha hydrogen for the reaction to occur. The reaction typically converts alkylbenzenes into carboxylic acids. ### Step-by-Step Solution: 1. **Identify the Compounds**: Let's denote the aromatic compounds as A, B, C, and D. 2. **Understand the Role of Alpha Hydrogen**: - Alpha hydrogens are the hydrogens attached to the carbon adjacent to the aromatic ring. - For KMnO4 to react, there must be at least one alpha hydrogen present. 3. **Analyze Each Compound**: - **Compound A**: - Contains two alpha hydrogens. - Since it has alpha hydrogens, it will react with KMnO4. - **Compound B**: - Contains three alpha hydrogens. - This compound will also react with KMnO4 due to the presence of alpha hydrogens. - **Compound C**: - Contains one alpha hydrogen. - Despite having two methyl groups, it still has one alpha hydrogen, so it will react with KMnO4. - **Compound D**: - Contains a tertiary butyl group with no alpha hydrogens. - Since there are no alpha hydrogens, this compound will not react with KMnO4. 4. **Conclusion**: - The compounds that will react with KMnO4 are A, B, and C. - The compound that will not react is D. ### Final Answer: - **Compounds that will react with KMnO4**: A, B, C - **Compound that will not react**: D

To determine which aromatic compounds will react with KMnO4, we need to analyze the presence of alpha hydrogens in each compound. KMnO4 is a strong oxidizing agent that requires at least one alpha hydrogen for the reaction to occur. The reaction typically converts alkylbenzenes into carboxylic acids. ### Step-by-Step Solution: 1. **Identify the Compounds**: Let's denote the aromatic compounds as A, B, C, and D. 2. **Understand the Role of Alpha Hydrogen**: ...
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