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From the following sequence of reactions...

From the following sequence of reactions,
[A] `(C_(6)H_(12))overset(HCl)(to)(B)(C_(6)H_(13)Cl)+(C)(C_(6)H_(13)Cl)` react with `AgNO_(3)` to give white ppt.
[B] `overset(Alc. KOH)(to)` (D) (An isomer of A) gives positive test with `Br_(2)//C Cl_(4)`
[D] `overset("Ozonolysis")(to)` (E) gives positive iodoform test and negative Fehling's test .
[A] `overset("Ozonolysis")(to)(F)+(G)` both F and G give positive Tollen's test.
`[F]+[G]overset(Conc. NaOH)underset(Delta)(to)HCOONa+"alcohol"`
The reaction involve in the F and G with the NaOH is :

A

Reimer-Tiemann reaction

B

Aldol condensation

C

Cannizzaro reaction

D

Perkin reaction

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the sequence of reactions involving organic compounds, we will break down the steps systematically. ### Step-by-Step Solution: 1. **Identify Compound A**: - Compound A is given as \(C_6H_{12}\). We need to determine its structure. The formula indicates that it has one degree of unsaturation (double bond equivalent = 1), which means it could either be a cyclic compound or have a double bond. 2. **Reaction of A with HCl**: - When \(C_6H_{12}\) reacts with HCl, it forms compound B, which is \(C_6H_{13}Cl\). This indicates that A is likely an alkene, and the addition of HCl results in the formation of an alkyl halide (B). 3. **Formation of Isomers**: - The reaction produces two isomers of \(C_6H_{13}Cl\) (compound B). This suggests that the addition of HCl can lead to different structural arrangements. 4. **Reaction of B with AgNO3**: - The compound B reacts with AgNO3 to give a white precipitate, indicating that B is likely a primary or secondary alkyl halide, which can undergo nucleophilic substitution. 5. **Formation of Compound D**: - Compound B, when treated with alcoholic KOH, undergoes elimination to form compound D, which is an isomer of A. Since D gives a positive test with Br2/CCl4, it indicates that D is likely an alkene. 6. **Ozonolysis of D**: - The ozonolysis of compound D yields compounds F and G. Since D gives a positive iodoform test and negative Fehling's test, it suggests that D has a methyl ketone or an aldehyde structure. 7. **Ozonolysis Products F and G**: - The ozonolysis of D breaks the double bond and forms two carbonyl compounds (aldehydes or ketones), which are F and G. Both F and G give positive Tollen's test, indicating that they are aldehydes. 8. **Reaction of F and G with Concentrated NaOH**: - The reaction of F and G with concentrated NaOH under heating leads to the formation of HCOONa (sodium formate) and an alcohol. This suggests that one of the compounds is oxidized to form a carboxylic acid salt, while the other is reduced to form an alcohol. 9. **Identify the Type of Reaction**: - The reaction between F and G with NaOH is indicative of the Cannizzaro reaction, where one aldehyde is oxidized to a carboxylic acid and the other is reduced to an alcohol. ### Conclusion: The reaction involved in the interaction of compounds F and G with concentrated NaOH is the **Cannizzaro reaction**.
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