Home
Class 12
CHEMISTRY
Calculate DeltaG^(@) for the following c...

Calculate `DeltaG^(@)` for the following cell:
`Fe|Fe^(2+)||Cu^(2+)|Cu`.
Given that: `E^(@)(Cu^(2+)//Cu)=+0*34V,E^(@)(Fe^(2+)//Fe)=-0*44V.

Text Solution

Verified by Experts

Step I. To calculate `EMF^(@)` and n cell is,
`Fe|Fe^(2+)||Cu^(2+)|Cu`
The cell reactions are,
Oxidation: `Fe(s) to Fe^(2+)(aq)+Cu(s)`
Reduction : `Cu^(2+)(aq)+2e^(-) to Cu(s)`
Overall: `Fe(s)+Cu^(2+)(aq)toFe^(2+)(aq)+Cu(s)`
Thus, n=2
`EMF^(@)=E^(@)(Cu^(2+)//Cu)-E^(@)(Fe^(2+)//Fe)`
`=0*34V-(-0*44V)`
`=0*78V`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    BETTER CHOICE PUBLICATION|Exercise FUEL CELLS|8 Videos
  • CO-ORDINATION COMPOUNDS

    BETTER CHOICE PUBLICATION|Exercise QUESTION FROM PREVIOUS BOARD EXAMINATION|59 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    BETTER CHOICE PUBLICATION|Exercise Question Bank (6.6 OXIDATION-REDUCTION)|15 Videos

Similar Questions

Explore conceptually related problems

Write the Nernst equation and calculate the emf of following cell at 298 K: Ni//Ni^(2+)(0.01M)||Cu^(2+)//Cu(0.01M) Given E^(@)(Cu^(2+)//Cu)=+0.34V,E^(@)(Ni^(2+)//Ni)=-0.025V

Calculate DeltaG and E_(cell) for the cell: AI//AI^(3+)(0.01M)||Fe^(2+)(0.02M)//Fe given that E^(@)(Al^(3+)//Al)=-1.66V and E^(@)(Fe^(2+)//Fe)=-0.44V

Write Nernst equation and calculate the e.m.f of the following cell at 298 K: Zn|Zn^(2+)(0.01M)||Fe^(2+)(0.005M)|Fe Given that: (Zn^(2+)//Zn)=-0.763V and E_(Fe^(2+)//Fe)^(@)=-0.44V" "log2=0.3010 .

Calculate the e.m.f. of the following cell at 298 K. Mg_((s))|Mg^(2+)(0.001M)||Cu^(2+)(0.0001M)|Cu_((s)) Given E^(@)(Cu^(2+)|Cu)=0.34V and E^(@)(Mg^(+)|Mg)=-2.37V .

Calculate the emf of cell, Al|Al^(3+)||Cu^(2+)|Cu Given : E^(@) (Al^(3)|Al) = - 1.66V and E^(@) (Cu^(2+)|Cu) = + 0.34 V

Write Nernst equation and calculate the e.m.f. of the following cell at 298 K: Cu(s)|Cu^(2+)(0.130M)||Ag^(+)(1.0xx10^(-4)M)|Ag(s) Given that: E_(Cu^(2+)//Cu)^(@)=+0.34V and E_(Ag^(+)//Ag)^(@)=+0.80V (log 0.130=-1.1139).

Derive Nernst equation for the following cell: NiNi^(2+)(0*2M)||Cu^(2+)(0*2M)|Cu .

The calculate the e.mf. Of the following cell at 298: Fe|Fe^(2+)(0.1M)||Ag^(2+)(0.1M)|Ag E_((Fe^(2+)//Fe))^(@)=-0.44V,E_((Ag^(+)//Ag))^(@)=0.80V .

Calculate the e.m.f. of the cell at 25^(@)C Cr|Cr^(3+)(0.1M)||Fe^(2+)(0.01M)|Fe Given E_((Cr^(2+)//Cr))^(@)=-0.75V,E_((Fe^(2+)//Fe))^(@)=-0.44

Calculate the e.m.f of the following cell at 298K 2Cr(s)+3Fe^(2+)(0.01M)rarr2Cr^(3+)(0.1M)+3Fe(s) Given: E^@(Cr^(3+)|Cr)=-0.75V , E^@(Fe^(2+)|Fe)=-0.45V .

BETTER CHOICE PUBLICATION-ELECTROCHEMISTRY-Numerical Problems
  1. The electrical resistance of a column of 0.05 mol L^(-1) NaOH solution...

    Text Solution

    |

  2. A conductivity cell has its electrodes 1 cm apart and each electrode h...

    Text Solution

    |

  3. Calculate DeltaG^(@) for the following cell: Fe|Fe^(2+)||Cu^(2+)|Cu....

    Text Solution

    |

  4. E^(@) values for Fe^(3+)//Fe^(2+) and Ag^(+)//Ag are 0.771 V and 0.8 r...

    Text Solution

    |

  5. The resistance of a 0.5 M solution of an electrolyte enclosed between ...

    Text Solution

    |

  6. E^(@) value for Cu^(2+)//Cu and Fe^(2+)//Fe are +0.34 V and -0.44 V re...

    Text Solution

    |

  7. A 0.05 M NaOH solution offered a resistance of 31.6 ohm ina conductivi...

    Text Solution

    |

  8. E^(@) values of Ni^(2+)//Ni and Cu^(2+)//Cu are -0.25 V and +0.34 V re...

    Text Solution

    |

  9. The resistance of a 0.5 M solution of an electrolyte in a conductivity...

    Text Solution

    |

  10. Represent the cell in which the following reaction takes place Mg(s) +...

    Text Solution

    |

  11. Represent the cell in which the following reaction takes place: Mg(s...

    Text Solution

    |

  12. Write Nernst equation and calculate the e.m.f. of the following cell a...

    Text Solution

    |

  13. The molar conductance of NaCl solution at different concentrations at ...

    Text Solution

    |

  14. Write Nernst equation and calculate e.m.f. of the cell at 298 k. Mg(...

    Text Solution

    |

  15. Complete the reaction :

    Text Solution

    |

  16. Write Nernst equation and calculate the e.m.f of the following cell at...

    Text Solution

    |

  17. Fill in the blanks:

    Text Solution

    |

  18. Calculate the standard Gibbs energy for the cell : Zn(s)+Zn^(2+)(aq)...

    Text Solution

    |

  19. Calculate the standard Gibbs energy for the cell : Zn(s)|Zn^(2+)(aq)...

    Text Solution

    |

  20. Calculate the standard Gibbs energy for the cell : Zn(s)|Zn^(2+)(aq)...

    Text Solution

    |