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Write Nernst equation and calculate the ...

Write Nernst equation and calculate the e.m.f of the following cell at 298 K:
`Zn|Zn^(2+)(0.01M)||Fe^(2+)(0.005M)|Fe`
Given that:
`(Zn^(2+)//Zn)=-0.763V and E_(Fe^(2+)//Fe)^(@)=-0.44V" "log2=0.3010`.

Text Solution

Verified by Experts

Cell representation is
`Az|Zn^(2+)(10^(-2)M)||Fe^(2+)(5xx10^(-3)M)De`
Cell reaction are,
Oxidation : `Zn(s) to Zn^(2+)(aq)+2e^(-)`
Reduction : `Fe^(2+)(aq)+Ze^(-) to Fe(s)`
Overall : `Zn(s)+Fe^(2+)(aq)toFe(s)+Zn^(2+)(aq)`
Here `n=2, and Q_(C)=([Zn^(2+)])/([Fe^(2+)])`
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BETTER CHOICE PUBLICATION-ELECTROCHEMISTRY-Numerical Problems
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  2. Complete the reaction :

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  4. Fill in the blanks:

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  9. Calculate the e.m.f. of the following cell at 298 K. Mg((s))|Mg^(2+)...

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  11. Calculate the e.m.f. of the following cell at 298 K, Mg|Mg^(2+)(0.13...

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  12. The lamda^(@) values of NaCl and NanO(3) are 126.5 and 121.6S" "cm^(2)...

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  13. The calculate the e.mf. Of the following cell at 298: Fe|Fe^(2+)(0.1...

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  14. Write the Nernst equation and calculate e.m.f of following cell at 298...

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