Home
Class 12
CHEMISTRY
The lamda^(@) values of KCl and KNO(3) a...

The `lamda^(@)` values of KCl and `KNO_(3)` are 149.9 and 144.9 S `cm^(2)mol^(-1)` respectively. Also `lamda^(@)` for `Cl^(-)` is 71.44 S `cm^(2)mol^(-1)`.The `lamda^(@)` value of `NO_(3)^(-)` ion.

Text Solution

Verified by Experts

`lamda_(m)^(@)(KCl)=lamda_(m)^(@)(K^(+))+lamda_(m)^(@)(Cl^(-))`
`lamda_(m)^(@)(K^(+))=lamda_(m)^(@)(KCl)-lamda_(m)^(@)(Cl^(-))`
`=(149.9-76.3)S" "cm^(2)mol^(-1)`
`=73.6"S "cm^(2)mol^(-1)`
`lamda_(m)^(@)(KNO_(3))=lamda_(m)^(@)(K^(+))+lamda_(m)^(@)(NO_(3)^(-))`
`lamda_(m)^(@)(NO_(3)^(-))=lamda_(m)^(@)(KNO_(3))-lamda_(m)^(@)(K^(+))`
`=(144.9-73.6)S" "cm^(2)mol^(-1)`
`=71.3S" "cm^(2)mol^(-1)`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    BETTER CHOICE PUBLICATION|Exercise FUEL CELLS|8 Videos
  • CO-ORDINATION COMPOUNDS

    BETTER CHOICE PUBLICATION|Exercise QUESTION FROM PREVIOUS BOARD EXAMINATION|59 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    BETTER CHOICE PUBLICATION|Exercise Question Bank (6.6 OXIDATION-REDUCTION)|15 Videos

Similar Questions

Explore conceptually related problems

The lamda^(@) values of NaCl and NanO_(3) are 126.5 and 121.6S" "cm^(2)mol^(-1) respectively. The lamda^(@) value of NO_(3)^(-) ion is 76.3 S cm^(2)mol^(-1) calculate lamda^(@)(Cl^(-)) .

The lamda^(@) values of KNO_(3) and LiNO_(3) are 145.0 and 110.1 S cm^(2)mol^(-1) respectively. The lamda^(@) value of K^(+) ion is 73.5"S "cm^(2)mol^(-1) . Calculate lamda^(@)(Li^(+)) .

A^@_m for NaCl, HC1 and NaAc are 126.4, 425.9 and 91.0 S cm^2 mol_-1 respectively. Calculate A^@ for HAc.

The value of (-3)^(-2) is (-1)/(9)

The limiting equivalent conductivity of NaCl, KCl and KBr are 126.5,150.0 and 151.5 S cm^(2) eq^(-1) , respectively. The limiting equivalent ionic conductance for Br^(-) is 78 S cm^(2) eq^(-1) . The limiting equivalent ionic conductance for Na^(+) ions would be :

BETTER CHOICE PUBLICATION-ELECTROCHEMISTRY-Numerical Problems
  1. The lamda^(@) values of KNO(3) and LiNO(3) are 145.0 and 110.1 S cm^(2...

    Text Solution

    |

  2. Calculate the e.m.f. of the following cell at 298 K. Mg((s))|Mg^(2+)...

    Text Solution

    |

  3. The lamda^(@) values of KCl and KNO(3) are 149.9 and 144.9 S cm^(2)mol...

    Text Solution

    |

  4. Calculate the e.m.f. of the following cell at 298 K, Mg|Mg^(2+)(0.13...

    Text Solution

    |

  5. The lamda^(@) values of NaCl and NanO(3) are 126.5 and 121.6S" "cm^(2)...

    Text Solution

    |

  6. The calculate the e.mf. Of the following cell at 298: Fe|Fe^(2+)(0.1...

    Text Solution

    |

  7. Write the Nernst equation and calculate e.m.f of following cell at 298...

    Text Solution

    |

  8. Write Nernst equation and calculate the e.m.f. of the following cell a...

    Text Solution

    |

  9. Write Nernst equation and calculate e.m.f. of the cell at 298 k. Mg(...

    Text Solution

    |

  10. Write Nernst equation and calculate the e.m.f of the following cell at...

    Text Solution

    |

  11. Write Nernst equation and calculate the e.m.f. of the following cell a...

    Text Solution

    |

  12. Calculate the e.m.f. of the cell at 25^(@)C Cr|Cr^(3+)(0.1M)||Fe^(2+)(...

    Text Solution

    |

  13. What is the amount of electricity required to deposit one mole of alum...

    Text Solution

    |

  14. A solution of Ni(NO3)2 is electrolysed between platinum electrodes usi...

    Text Solution

    |

  15. What is the amount of electricity required to deposit one mole of alum...

    Text Solution

    |

  16. What mass of zinc can be produced by the electrolysis of zinc sulphate...

    Text Solution

    |

  17. What is the amount of electricity required to deposit one mole of Zinc...

    Text Solution

    |

  18. A solution of CuSO4 is electrolysed for 10 minutes with a current of 1...

    Text Solution

    |

  19. Calculate the cell e.m.f. and DeltaG for the cell reaction at 25^(@)C ...

    Text Solution

    |

  20. The resistance of a 0.5 M solution of an electrolyte in a conductivity...

    Text Solution

    |