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Calculate the e.m.f. of the cell at 25^(...

Calculate the e.m.f. of the cell at `25^(@)C` `Cr|Cr^(3+)(0.1M)||Fe^(2+)(0.01M)|Fe`
Given `E_((Cr^(2+)//Cr))^(@)=-0.75V,E_((Fe^(2+)//Fe))^(@)=-0.44`

Text Solution

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Cell representation is,
`Cr|Cr^(3+)(0.1M)||Fe^(2+)(0.01M)|Fe`
Cell reaction are,
`Cr(s)toCr^(3+)(aq)+3e^(-)]xx2`
`Fe^(2+)(aq)+2e^(-) to Fe(s)]xx3`
`2Cr(s)+3Fe^(2+)(aq)to2Cr^(3+)(aq)+3Fe(s)`
Here, n=5
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