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Discuss oxidation of primary,secondary a...

Discuss oxidation of primary,secondary and tertiary alcohols.

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Oxidation of `1^(@)and2^(@)` alcohols can easily be carried out by common oxidising agents like `KMnO_(4)//H^(+)orK_(2)Cr_(2)O_(7)//H^(+)`.
Oxidation of `1^(@)` alcohols first give aldehyde and then carboxylic acid For example ,
`underset(("Ethanol"))underset("Ethyl alcohol")(CH_(3)CH_(2)OH)underset(-H_(2)O)overset([O])tounderset(("Ethanol"))underset("Acetaldehyde")(CH_(3)CHO)overset([O])tounderset("Ethanoicacid")underset("Aceticacid")(CH_(3)COOH)`
Oxidation of `2^(@)` alcohols give ketones .For example ,

Oxidation of `3^(@)` alcohols is not possible with ordinary oxidising agents .Under drastic conditions oxidation of `3^(@)` alcohols yield ketones and carboxylic acids with lesser number of carbon atoms .
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BETTER CHOICE PUBLICATION-ALCOHOLS , PHENOLS AND ETHERS -11. 4 . 3 . CHEMICAL PROPERTIES
  1. How alcohols react with (i) Carboxylic acids (ii) Acid anh...

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  2. Discuss oxidation of primary,secondary and tertiary alcohols.

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  3. Discuss oxidation of primary,secondary and tertiary alcohols.

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  4. How will you convert ethanol to ethanoic acid ?

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  5. What happens when phenol is treated with conc . HNO(3) ?

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  6. How is phenol converted into picric acid ?

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  7. What is Fries Rearrangement .

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  8. Write the following reactions : Phenol with phthallic anhydride.

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  9. How alcohols react with SOCl(2)

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  10. How alcohols react with PCl(5)

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  11. Write the structure of penta-1,3-diene

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  12. Explain Lucas test to distinguish between 1^@, 2^@ and 3^@ alcohols.

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  13. How will you distinguish primary, secondary and tertiary alcohols by d...

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  14. Explain Victor Meyer’s test for secondary (2^@) alcohol.

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  15. How will you distinguish secondary and tertiary alcohols are pas...

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  16. How will you distinguish secondary and tertiary alcohols are pas...

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  17. How will you distinguish primary, secondary and tertiary alcohols by d...

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  18. Write the reaction of primary , secondary and tertiary alcohols w...

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  19. Writing chemical equations What happen when phenol is treated with...

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  20. How will you convert ethanol to ethane ?

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