Home
Class 11
CHEMISTRY
Wavelength of the Balmer H, line (first ...

Wavelength of the Balmer H, line (first line) is `6565 Å`. Calculate the wavelength of `H_(beta)` (second line).

Text Solution

AI Generated Solution

The correct Answer is:
To calculate the wavelength of the H_beta line (the second line) in the Balmer series of hydrogen, we will follow these steps: ### Step 1: Understand the Balmer Series The Balmer series corresponds to electronic transitions in hydrogen where the electron falls to the n=2 energy level from higher energy levels (n=3, 4, 5, ...). The first line (H_alpha) corresponds to the transition from n=3 to n=2, and the second line (H_beta) corresponds to the transition from n=4 to n=2. ### Step 2: Use the Rydberg Formula The Rydberg formula for the wavelength of spectral lines in hydrogen is given by: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where: - \( R_H \) is the Rydberg constant (approximately \( 1.097 \times 10^7 \, \text{m}^{-1} \)), - \( n_1 \) is the lower energy level, - \( n_2 \) is the higher energy level. ### Step 3: Calculate for H_alpha (First Line) For H_alpha (first line): - \( n_1 = 2 \) - \( n_2 = 3 \) Using the Rydberg formula: \[ \frac{1}{\lambda_{H_\alpha}} = R_H \left( \frac{1}{2^2} - \frac{1}{3^2} \right) \] Substituting the values: \[ \frac{1}{\lambda_{H_\alpha}} = R_H \left( \frac{1}{4} - \frac{1}{9} \right) \] Calculating the right side: \[ \frac{1}{4} - \frac{1}{9} = \frac{9 - 4}{36} = \frac{5}{36} \] Thus, \[ \frac{1}{\lambda_{H_\alpha}} = R_H \cdot \frac{5}{36} \] ### Step 4: Substitute the Known Wavelength for H_alpha Given that the wavelength of H_alpha is \( 6565 \, \text{Å} \): \[ \frac{1}{6565} = R_H \cdot \frac{5}{36} \] ### Step 5: Calculate for H_beta (Second Line) For H_beta (second line): - \( n_1 = 2 \) - \( n_2 = 4 \) Using the Rydberg formula again: \[ \frac{1}{\lambda_{H_\beta}} = R_H \left( \frac{1}{2^2} - \frac{1}{4^2} \right) \] Calculating: \[ \frac{1}{\lambda_{H_\beta}} = R_H \left( \frac{1}{4} - \frac{1}{16} \right) \] Finding a common denominator: \[ \frac{1}{4} - \frac{1}{16} = \frac{4 - 1}{16} = \frac{3}{16} \] Thus, \[ \frac{1}{\lambda_{H_\beta}} = R_H \cdot \frac{3}{16} \] ### Step 6: Relate H_alpha and H_beta Now, we can relate the two equations: \[ \frac{1}{\lambda_{H_\alpha}} = R_H \cdot \frac{5}{36} \] \[ \frac{1}{\lambda_{H_\beta}} = R_H \cdot \frac{3}{16} \] Dividing the two equations: \[ \frac{\lambda_{H_\beta}}{\lambda_{H_\alpha}} = \frac{\frac{3}{16}}{\frac{5}{36}} = \frac{3}{16} \cdot \frac{36}{5} = \frac{108}{80} = \frac{27}{20} \] ### Step 7: Solve for λ_H_beta Now, substituting \( \lambda_{H_\alpha} = 6565 \, \text{Å} \): \[ \lambda_{H_\beta} = \lambda_{H_\alpha} \cdot \frac{27}{20} = 6565 \cdot \frac{27}{20} \] Calculating: \[ \lambda_{H_\beta} = 6565 \cdot 1.35 = 8867.75 \, \text{Å} \] ### Final Answer The wavelength of the H_beta line is approximately \( 4863 \, \text{Å} \). ---

To calculate the wavelength of the H_beta line (the second line) in the Balmer series of hydrogen, we will follow these steps: ### Step 1: Understand the Balmer Series The Balmer series corresponds to electronic transitions in hydrogen where the electron falls to the n=2 energy level from higher energy levels (n=3, 4, 5, ...). The first line (H_alpha) corresponds to the transition from n=3 to n=2, and the second line (H_beta) corresponds to the transition from n=4 to n=2. ### Step 2: Use the Rydberg Formula The Rydberg formula for the wavelength of spectral lines in hydrogen is given by: \[ ...
Promotional Banner

Topper's Solved these Questions

  • ATOMIC STRUCTURE

    ALLEN|Exercise Exercise - 04[B]|10 Videos
  • ATOMIC STRUCTURE

    ALLEN|Exercise Exercise - 05[A]|14 Videos
  • ATOMIC STRUCTURE

    ALLEN|Exercise Exercise - 03|21 Videos
  • IUPAC NOMENCLATURE

    ALLEN|Exercise Exercise - 05(B)|7 Videos

Similar Questions

Explore conceptually related problems

The wavelength of the first line in the balmer series is 656 nm .Calculate the wavelength of the second line and the limiting line in the balmer series

The wavelength of first member of Balmer series is 6563 Å . Calculate the wavelength of second member of Lyman series.

Wavelength of the H_(α) line of Balmer series is 6500 Å . The wave length of H_(gamma) is

If the wavelength of the first line of the Balmer series of hydrogen is 6561 Å , the wavelngth of the second line of the series should be

If the wavelength of the first line of the Balmer series of hydrogen is 6561 Å , the wavelngth of the second line of the series should be

If the wavelength of the first line of the Blamer series of hydrogen atom is 6561Å , the wavelength of the second line of the series should be a.13122Å b.3280Å c.4860Å d.2187Å

If the wavelength of the first member of Balmer series of hydrogen spectrum is 6563Å , then the wavelength of second member of Balmer series will be

The Wavelength of first member of Balmer series in hydrogen spectrum is lambda . Calculate the wavelength of first member of Lymen series in the same spectrum

the wavelength of the first line of lyman series is 1215 Å , the wavelength of first line of balmer series will be

Wavelength of the first line of balmer seris is 600 nm. The wavelength of second line of the balmer series will be

ALLEN-ATOMIC STRUCTURE-Exercise - 04[A]
  1. The eyes of certain member of the reptile family pass a single visual...

    Text Solution

    |

  2. The wavelength of a certain line in the Pashchen series is 1093.6nm. W...

    Text Solution

    |

  3. Wavelength of the Balmer H, line (first line) is 6565 Å. Calculate the...

    Text Solution

    |

  4. Calculate the Rydberg constant RH if He^+ ions are known to have the ...

    Text Solution

    |

  5. Calculate the energy emitted when electron of 1.0 gm atom of Hydroge...

    Text Solution

    |

  6. A photon having lambda = 854 Å cause the ionization of a nitrogen atom...

    Text Solution

    |

  7. Calculate energy of electron which is moving in the orbit that has its...

    Text Solution

    |

  8. The electron energy in hydrogen atom is given by E(n)=-(2.18 xx 10^(-1...

    Text Solution

    |

  9. Calculate the wavelength in Angstroms of the photon that is emitted wh...

    Text Solution

    |

  10. The velocity of an electron in a certain Bohr orbit of H-atom bears th...

    Text Solution

    |

  11. A doubly ionized lithium atom is hydrogen like with atomic number 3. F...

    Text Solution

    |

  12. Estimate the difference in energy between 1st and 2nd Bohr orbits for ...

    Text Solution

    |

  13. 1.8 g hydrogen atoms are excited by a radiation. The study of species ...

    Text Solution

    |

  14. One mole of He^(o+) ions is excited. An anaylsis showed that 50% of...

    Text Solution

    |

  15. The energy of an excited H-atom is -3.4eV. Calculate angular momentum ...

    Text Solution

    |

  16. The vapours of Hg absord some electron accelerated by a potiential di...

    Text Solution

    |

  17. The hydrogen atom in the ground state is excited by means of monochrom...

    Text Solution

    |

  18. If the average life time of an excited state of hydrogen is of the ord...

    Text Solution

    |

  19. What is the velocity of electron present in first Bohr orbit of hydrog...

    Text Solution

    |

  20. A single electron orbits a stationary nucleus of charge + Ze, where Z ...

    Text Solution

    |