Home
Class 11
CHEMISTRY
Calculate the energy emitted when elect...

Calculate the energy emitted when electron of 1.0 gm atom of Hydrogen undergo transition giving the spectrtal lines of lowest energy is visible region of its atomic spectra. Given that, `R_(H)`=`1.1xx10^(7) m^(-1)`,` c=3xx10^8m//sec`,` h=6.625xx10^(-34) Jsec`.

Text Solution

AI Generated Solution

The correct Answer is:
To calculate the energy emitted when an electron in a hydrogen atom undergoes a transition that gives rise to the spectral lines in the visible region, we will follow these steps: ### Step 1: Identify the Transition The lowest energy transition in the visible region for hydrogen occurs in the Balmer series, specifically from the third energy level (n2 = 3) to the second energy level (n1 = 2). ### Step 2: Use the Rydberg Formula The Rydberg formula for the wavelength (λ) of the emitted light is given by: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] Substituting \( n_1 = 2 \) and \( n_2 = 3 \): \[ \frac{1}{\lambda} = R_H \left( \frac{1}{2^2} - \frac{1}{3^2} \right) = R_H \left( \frac{1}{4} - \frac{1}{9} \right) \] Calculating the right-hand side: \[ \frac{1}{4} - \frac{1}{9} = \frac{9 - 4}{36} = \frac{5}{36} \] Thus, \[ \frac{1}{\lambda} = R_H \cdot \frac{5}{36} \] ### Step 3: Substitute the Rydberg Constant Given \( R_H = 1.1 \times 10^7 \, \text{m}^{-1} \): \[ \frac{1}{\lambda} = 1.1 \times 10^7 \cdot \frac{5}{36} \] Calculating \( \frac{1}{\lambda} \): \[ \frac{1}{\lambda} = \frac{5.5 \times 10^7}{36} \approx 1.52778 \times 10^6 \, \text{m}^{-1} \] ### Step 4: Calculate the Wavelength (λ) Taking the reciprocal gives us the wavelength: \[ \lambda = \frac{1}{1.52778 \times 10^6} \approx 6.54 \times 10^{-7} \, \text{m} \] ### Step 5: Calculate the Energy (E) Using the formula for energy: \[ E = \frac{hc}{\lambda} \] Substituting \( h = 6.625 \times 10^{-34} \, \text{J s} \) and \( c = 3 \times 10^8 \, \text{m/s} \): \[ E = \frac{(6.625 \times 10^{-34}) \cdot (3 \times 10^8)}{6.54 \times 10^{-7}} \] Calculating the energy: \[ E \approx \frac{1.9875 \times 10^{-25}}{6.54 \times 10^{-7}} \approx 3.03 \times 10^{-19} \, \text{J} \] ### Step 6: Calculate the Energy for 1 Gram of Hydrogen To find the total energy emitted for 1 gram of hydrogen, we need to multiply the energy per atom by Avogadro's number (\( N_A = 6.022 \times 10^{23} \, \text{atoms/mol} \)): \[ E_{\text{total}} = E \times N_A = (3.03 \times 10^{-19} \, \text{J}) \times (6.022 \times 10^{23} \, \text{atoms/mol}) \] Calculating the total energy: \[ E_{\text{total}} \approx 18.25 \, \text{J} \] ### Final Answer The energy emitted when an electron of 1.0 gram of hydrogen undergoes the transition is approximately **18.25 J**. ---

To calculate the energy emitted when an electron in a hydrogen atom undergoes a transition that gives rise to the spectral lines in the visible region, we will follow these steps: ### Step 1: Identify the Transition The lowest energy transition in the visible region for hydrogen occurs in the Balmer series, specifically from the third energy level (n2 = 3) to the second energy level (n1 = 2). ### Step 2: Use the Rydberg Formula The Rydberg formula for the wavelength (λ) of the emitted light is given by: ...
Promotional Banner

Topper's Solved these Questions

  • ATOMIC STRUCTURE

    ALLEN|Exercise Exercise - 04[B]|10 Videos
  • ATOMIC STRUCTURE

    ALLEN|Exercise Exercise - 05[A]|14 Videos
  • ATOMIC STRUCTURE

    ALLEN|Exercise Exercise - 03|21 Videos
  • IUPAC NOMENCLATURE

    ALLEN|Exercise Exercise - 05(B)|7 Videos

Similar Questions

Explore conceptually related problems

Find the energy released (in erg) when 2.0 g atom of hydrogen undergoes transition giving a spectral line of the lowest energy in the visible region of its atomic spectra

Calculate the energy emitted when electrons of 1.0 g 1 of hydrogen transition giving spectrum lines of the lowest in the visible regain of its atomic spectrum R_(H) = 1.1 xx 10^(7) m^(-1) , c= 3 xx 10^(8) m s^(-1) and h = 6.62 xx 10^(-34) J s

The energy of n^(th) orbit is given by E_(n) = ( -Rhc)/(n^(2)) When electron jumpsfrom one orbit to another orbit then wavelength associated with the radiation is given by (1)/(lambda) = RZ^(2)((1)/(n_(1)^(2)) - (1)/ (n_(2)^(2))) When electron of 1.0 gm atom of Hydrogen undergoes transition giving the spectral line of lowest energy in visible region of its atomic spectra, the wavelength of radiation is

Find the two longest wavelength ("in" Å) emitted when hydrogen atom make transition and the spectrum lines lie in the visible region (R = 1.097 xx 10^(7) m^(-1))

Calculate wavelength of the radiation corresponding to the speciral line of the lowest frequency in lyman series in the spectrum of a hydrogen atom (R_(H) = 109677 cm^(-1), c = 3 xx 10^(8) m s^(-1), Z = 1)

What is the energy difference and the frequency of light emitted when the electron in a hydrogen atom undergoes transition from the energy level n = 4 to the energy n = 3 given that the value of Rydberg constant is 1.0974 xx 10^(7)m^(-1) ?

The frequency of radiation emiited when the electron falls n =4 to n=1 in a hydrogen atom will be ( given ionization energy of H= 2.18 xx 10 ^(-18)J "atom "^(-1) and h= 6.625 xx 10 ^(-34)Js)

Heat treatment of muscular pain involves radiation of wavelength of about 900nm. Which spectral line of H-atom is suitable for this purpose? [R_H=1xx10^5 cm^(-1), h=6.6xx10^(-34) Js, c=3xx10^8 ms^(-1) ]

Heat treatment of muscular pain involves radiation of wavelength of about 900nm. Which spectral line of H-atom is suitable for this purpose? [R_H=1xx10^5 cm^(-1), h=6.6xx10^(-34) Js, c=3xx10^8 ms^(-1) ]

Calculate the wavelength and energy for radiation emitted for the electron transition from infinite (oo) to stationary state of the hydrogen atom R = 1.0967 xx 10^(7) m^(-1), h = 6.6256 xx 10^(-34) J s and c = 2.979 xx 10^(8) m s^(-1)

ALLEN-ATOMIC STRUCTURE-Exercise - 04[A]
  1. Wavelength of the Balmer H, line (first line) is 6565 Å. Calculate the...

    Text Solution

    |

  2. Calculate the Rydberg constant RH if He^+ ions are known to have the ...

    Text Solution

    |

  3. Calculate the energy emitted when electron of 1.0 gm atom of Hydroge...

    Text Solution

    |

  4. A photon having lambda = 854 Å cause the ionization of a nitrogen atom...

    Text Solution

    |

  5. Calculate energy of electron which is moving in the orbit that has its...

    Text Solution

    |

  6. The electron energy in hydrogen atom is given by E(n)=-(2.18 xx 10^(-1...

    Text Solution

    |

  7. Calculate the wavelength in Angstroms of the photon that is emitted wh...

    Text Solution

    |

  8. The velocity of an electron in a certain Bohr orbit of H-atom bears th...

    Text Solution

    |

  9. A doubly ionized lithium atom is hydrogen like with atomic number 3. F...

    Text Solution

    |

  10. Estimate the difference in energy between 1st and 2nd Bohr orbits for ...

    Text Solution

    |

  11. 1.8 g hydrogen atoms are excited by a radiation. The study of species ...

    Text Solution

    |

  12. One mole of He^(o+) ions is excited. An anaylsis showed that 50% of...

    Text Solution

    |

  13. The energy of an excited H-atom is -3.4eV. Calculate angular momentum ...

    Text Solution

    |

  14. The vapours of Hg absord some electron accelerated by a potiential di...

    Text Solution

    |

  15. The hydrogen atom in the ground state is excited by means of monochrom...

    Text Solution

    |

  16. If the average life time of an excited state of hydrogen is of the ord...

    Text Solution

    |

  17. What is the velocity of electron present in first Bohr orbit of hydrog...

    Text Solution

    |

  18. A single electron orbits a stationary nucleus of charge + Ze, where Z ...

    Text Solution

    |

  19. A stationary hydrogen atom emits photon corresponding to the first lin...

    Text Solution

    |

  20. To what series does the spectral lines of atomic hydrogen belong if ...

    Text Solution

    |