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The hydrogen atom in the ground state is...

The hydrogen atom in the ground state is excited by means of monochromatic radiation of wavelength `xA_(0)` The resulting spectrum consists of 15 different lines. Calculate the value of x.

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To solve the problem, we need to determine the wavelength \( x \) of monochromatic radiation that excites a hydrogen atom from its ground state, resulting in 15 different spectral lines. ### Step-by-Step Solution: 1. **Understanding the Number of Lines**: The number of spectral lines \( N \) produced when an electron transitions from a higher energy level \( n_2 \) to a lower energy level \( n_1 \) is given by the formula: \[ N = \frac{n_2(n_2 - n_1)}{2} \] Here, since the electron is excited from the ground state (where \( n_1 = 1 \)), we can set \( n_1 = 1 \). 2. **Setting Up the Equation**: Given that \( N = 15 \) and \( n_1 = 1 \), we can substitute these values into the equation: \[ 15 = \frac{n_2(n_2 - 1)}{2} \] Multiplying both sides by 2 gives: \[ 30 = n_2(n_2 - 1) \] Rearranging this, we get: \[ n_2^2 - n_2 - 30 = 0 \] 3. **Solving the Quadratic Equation**: We can solve the quadratic equation \( n_2^2 - n_2 - 30 = 0 \) using the quadratic formula: \[ n_2 = \frac{-b \pm \sqrt{b^2 - 4ac}}{2a} \] Here, \( a = 1, b = -1, c = -30 \): \[ n_2 = \frac{1 \pm \sqrt{(-1)^2 - 4 \cdot 1 \cdot (-30)}}{2 \cdot 1} \] \[ n_2 = \frac{1 \pm \sqrt{1 + 120}}{2} \] \[ n_2 = \frac{1 \pm \sqrt{121}}{2} \] \[ n_2 = \frac{1 \pm 11}{2} \] This gives us two possible solutions: \[ n_2 = 6 \quad \text{(since n must be positive)} \] 4. **Calculating the Wavelength**: Now that we have \( n_2 = 6 \) and \( n_1 = 1 \), we can use the Rydberg formula to calculate the wavelength \( \lambda \): \[ \frac{1}{\lambda} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] For hydrogen, \( R = 1.097 \times 10^7 \, \text{m}^{-1} \). Substituting the values: \[ \frac{1}{\lambda} = R \left( \frac{1}{1^2} - \frac{1}{6^2} \right) \] \[ \frac{1}{\lambda} = R \left( 1 - \frac{1}{36} \right) \] \[ \frac{1}{\lambda} = R \left( \frac{36 - 1}{36} \right) = R \left( \frac{35}{36} \right) \] \[ \frac{1}{\lambda} = \frac{35}{36} R \] 5. **Finding the Wavelength**: Now, substituting the value of \( R \): \[ \lambda = \frac{36}{35 R} \] Converting \( R \) into angstroms: \[ R = 1.097 \times 10^7 \, \text{m}^{-1} = 912 \, \text{Å}^{-1} \] Thus, \[ \lambda = \frac{36}{35 \times 912} \, \text{Å} \] \[ \lambda = \frac{36}{31920} \approx 0.00113 \, \text{Å}^{-1} \] Finally, calculating gives us: \[ \lambda \approx 2937.3 \, \text{Å} \] ### Final Answer: The value of \( x \) is approximately \( 2937.3 \, \text{Å} \).

To solve the problem, we need to determine the wavelength \( x \) of monochromatic radiation that excites a hydrogen atom from its ground state, resulting in 15 different spectral lines. ### Step-by-Step Solution: 1. **Understanding the Number of Lines**: The number of spectral lines \( N \) produced when an electron transitions from a higher energy level \( n_2 \) to a lower energy level \( n_1 \) is given by the formula: \[ N = \frac{n_2(n_2 - n_1)}{2} ...
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ALLEN-ATOMIC STRUCTURE-Exercise - 04[A]
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