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Which of the following names are correct...

Which of the following names are correct for the compound :
`CH_(3)-overset(O)overset(||)(C)-CH_(2)-COOH`

A

3-ketobutan-1-oic acid

B

4-Carboxy butan-2-one

C

3-oxo butan-1-oic acid

D

3-Carboxy acetone

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct IUPAC names for the compound `CH₃-C(=O)-CH₂-COOH`, we need to follow the IUPAC nomenclature rules step by step. ### Step-by-Step Solution: 1. **Identify the Functional Groups**: The compound contains two functional groups: a carboxylic acid (-COOH) and a ketone (C=O). The carboxylic acid takes precedence over the ketone in naming. 2. **Number the Carbon Chain**: Start numbering the carbon chain from the end closest to the carboxylic acid group. This gives us: - C1: COOH - C2: CH₂ - C3: C=O (ketone) - C4: CH₃ Thus, the numbering is as follows: - C1: COOH - C2: CH₂ - C3: C=O (ketone) - C4: CH₃ 3. **Determine the Parent Chain**: The longest carbon chain that includes both functional groups is four carbons long, which corresponds to butanoic acid. 4. **Assign the Suffix and Prefix**: - The suffix for the carboxylic acid is “-oic acid”. - The ketone can be indicated as “oxo” or “keto”. Here, we will use “oxo” as a prefix. 5. **Combine the Information**: - The carboxylic acid is at position 1. - The ketone is at position 3. Therefore, the correct name is **3-oxo-butanoic acid**. 6. **Check the Other Options**: - **3-ketobutanoic acid**: This is incorrect because the correct prefix for the ketone is "oxo" when naming alongside a carboxylic acid. - **4-carboxybutan-2-one**: This is incorrect because the carboxylic acid should be prioritized over the ketone. - **3-oxo-butan-1-oic acid**: This is correct as it indicates the correct positions of the functional groups. ### Final Answer: The correct names for the compound are: - 3-oxo-butanoic acid - 3-oxo-butan-1-oic acid
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