Home
Class 12
CHEMISTRY
Calculate the equilibrium constant for t...

Calculate the equilibrium constant for the reaction at 298K.
`Zn(s) +Cu^(2+)(aq) hArr Zn^(2+)(aq) +Cu(s)`
Given, `E_(Zn^(2+)//Zn)^(@) =- 0.76V` and `E_(Cu^(2+)//Cu)^(@) = +0.34 V`

Text Solution

AI Generated Solution

To calculate the equilibrium constant for the reaction at 298 K, we can follow these steps: ### Step 1: Write the half-reactions and identify the anode and cathode The given reaction is: \[ \text{Zn(s)} + \text{Cu}^{2+}(aq) \rightleftharpoons \text{Zn}^{2+}(aq) + \text{Cu(s)} \] The half-reactions are: 1. Oxidation (anode): ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    ALLEN|Exercise COMPREHENSION TYPE|18 Videos
  • ELECTROCHEMISTRY

    ALLEN|Exercise INTEGER TYPE|18 Videos
  • ELECTROCHEMISTRY

    ALLEN|Exercise EXERCISE -05 [B]|38 Videos
  • CHEMISTRY AT A GLANCE

    ALLEN|Exercise ORGANIC CHEMISTRY|472 Videos
  • HYDROCARBON

    ALLEN|Exercise MCQ|15 Videos

Similar Questions

Explore conceptually related problems

Calculate the equilibrium constant for the reaction at 298 K Zn(s)+Cu^(2+)(aq)harr Zn^(2+)(aq)+Cu(s) Given " " E_(Zn^(2+)//Zn)^(@)=-0.76 V and E_(Cu^(2+)//Cu)^(@)=+0.34 V

Calculate the equilibrium constant for the reaction: Cd^(2+) (aq) +Zn(s) hArr Zn^(2+) (aq) +Cd (s) If E_(Cd^(2+)//Cd)^(Theta) = -0.403V E_(Zn^(2+)//Zn)^(Theta) = -0.763 V

Calculate the DeltaG^(@) and equilibrium constant of the reaction at 27^(@)C Mg+ Cu^(+2) hArr Mg^(+2) + Cu E_(Mg^(2+)//Mg)^(@) = -2.37V, E_(Cu^(2+)//Cu)^(@) = +0.34V

Calculate DeltaG^(@) for the reaction : Cu^(2+)(aq) +Fe(s) hArr Fe^(2+)(aq) +Cu(s) . Given that E_(Cu^(2+)//Cu)^(@) = 0.34 V , E_(Fe^(+2)//Fe)^(@) =- 0.44 V

(a) Calculate Delta G^@ for the reaction Zn (s) + Cu^(2+) (aq) rarr Zn^(2+) + Cu(s) Given: E^@ for (Zn^(2+))//Zn = -0.76 V and E^@ for (Cu^(2+))//Cu = +0.34 V R= 8.314 JK^-1 mol^(-1) F= 96500 Cmol^(-1) (b) give two advantages of fuel cells.

Calculate the maximum work that can be obtained from the daniell call given below, Zn(s)|Zn^(2+)(aq)||Cu^(2+)(aq)|Cu(s) . Given that E_(Zn^(2+)//Zn)^(@)=-0.76V and E_(Cu^(2+)//Cu)^(@)=+0.34V .

The equilibrium constant of the reaction : Zn(s)+2Ag^(+)(aq)toZn(aq)+2Ag(s),E^(@)=1.50V at 298 K is

Can a solution of 1 M ZnSO_(4) be stored in a vessel made of copper ? Given that E_(Zn^(+2)//Zn)^(@) =-0.76V and E_(Cu^(+2)//Cu)^(@)=0.34 V

Calculate DeltaG^(@) for the reaction : Cu^(2+)(aq) +Fe(s) hArr Fe^(2+)(aq) +Cu(s) . Given that E^(@)Cu^(2+)//Cu = 0.34 V , E_(Fe^(+2)//Fe)^(@) =- 0.44 V

Calculate the standard free enegry change for the reaction: Zn + Cu^(2+)(aq) rarr Cu+Zn^(2+) (aq), E^(Theta) = 1.20V

ALLEN-ELECTROCHEMISTRY-MISCELLANEOUS SOLVED EXAMPLES
  1. Given the standard electrode potentials K^(+)//K=-2.93V,Ag^(+)//Ag=0...

    Text Solution

    |

  2. A cell is prepared by dipping a copper rod in 1 MCuSO(4) solution and ...

    Text Solution

    |

  3. Predict whether the following reaction can occur under standard condit...

    Text Solution

    |

  4. Given that, Co^(3+) +e^(-)rarr Co^(2+) , E^(@) = +1.82 V 2H(2)O rarr...

    Text Solution

    |

  5. The measured e.m.f. at 25^(@)C for the cell reaction, Zn(s) +XCu^(2+...

    Text Solution

    |

  6. Calculate DeltaG^(@) for the reaction : Cu^(2+)(aq) +Fe(s) hArr Fe^(2+...

    Text Solution

    |

  7. A solution of copper (II) sulphate is electrolysed between copper elec...

    Text Solution

    |

  8. Calculate the equilibrium constant for the reaction at 298K. Zn(s) +...

    Text Solution

    |

  9. Calculate the cell e.m.f. and DeltaG for the cell reaction at 298K for...

    Text Solution

    |

  10. The EMF of a cell corresponding to the reaction : Zn((s)) + 2H((aq))^(...

    Text Solution

    |

  11. Find the standard electrode potential of MnO(4)^(c-)|MnO(2). The stand...

    Text Solution

    |

  12. The half cell potential of a half-cell A^(x+), A^((x+n)+)|Pt were foun...

    Text Solution

    |

  13. Consider the given data. {:(,"Half-cell reaction","Standard reductio...

    Text Solution

    |

  14. Specific conductance of 10^(-4)M n-Butyric acid aqueous solution is 1....

    Text Solution

    |

  15. How much time is required for complete decomposition of 4 moles of wat...

    Text Solution

    |

  16. The cell Pt|H(2)(g) (1atm)|H^(+), pH = x || Normal calomal electrode h...

    Text Solution

    |

  17. The specific conductivity of a saturated AgCl solution if found to be ...

    Text Solution

    |

  18. Consider the following standard reduction potentials:- {:(Fe^(2+)+2e...

    Text Solution

    |

  19. Find ^^(m)^(oo) ("in" Omega^(-1) cm^(2) mol^(-1)) for strong electroyt...

    Text Solution

    |

  20. 20 Ml of KOH solution was titrated with 0.20 M H(2)SO(4) solution in a...

    Text Solution

    |