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Math the following....

Math the following.

A

`{:(Column-I,Column-II),((Reactions),"(Characteristics)"),("Finkelstein reaction",(p)"Electrophilic catalysis"):}`

B

`{:(Column-I,Column-II),((Reactions),"(Characteristics)"),("Darzens procedure",(q)"Halide exchange"):}`

C

`{:(Column-I,Column-II),((Reactions),"(Characteristics)"),("Swarts reaction",(r)"Radical decawrboxylation"):}`

D

`{:(Column-I,Column-II),((Reactions),"(Characteristics)"),("Hunsdiecker reaction",(s)"Bimolecular substitution with retention"):}`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the matching question regarding the reactions and their characteristics, we will analyze each reaction one by one and match them with their corresponding descriptions. ### Step-by-Step Solution: 1. **Finkelstein Reaction:** - **Description:** The Finkelstein reaction involves the exchange of halogens. Specifically, it is the reaction of an alkyl halide (RCH2X) with sodium iodide (NaI) to produce an iodide compound (RCH2I) and sodium halide (NaX). - **Characteristic:** This reaction is characterized as a halogen exchange reaction. - **Match:** Finkelstein reaction → Q 2. **Darzen's Process:** - **Description:** Darzen's process involves the conversion of alcohol (e.g., CH3CH2OH) to an alkyl halide using thionyl chloride (SOCl2) in the presence of a base like pyridine. This process results in the formation of an alkyl halide with retention of configuration. - **Characteristic:** This reaction is an example of bimolecular nucleophilic substitution with retention (SNI mechanism). - **Match:** Darzen's process → S 3. **Swartz Reaction:** - **Description:** The Swartz reaction involves the reaction of an alkyl halide (RCH2X) with silver fluoride (AgF) or antimony trifluoride (SbF3) to produce a fluoro compound (RCH2F). This reaction is not a simple halogen exchange but involves electrophilic substitution. - **Characteristic:** This reaction is characterized as electrophilic catalysis. - **Match:** Swartz reaction → P 4. **Hans Dekker Reaction:** - **Description:** The Hans Dekker reaction involves the reaction of a silver salt of a carboxylic acid (R-COOAg) with bromine (Br2) in the presence of carbon tetrachloride (CCl4). This process results in the decarboxylation of the carboxylic acid, producing a product with one less carbon atom than the original substrate. - **Characteristic:** This reaction is an example of radical decarboxylation. - **Match:** Hans Dekker reaction → R ### Final Matches: - Finkelstein Reaction → Q - Darzen's Process → S - Swartz Reaction → P - Hans Dekker Reaction → R
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ALLEN-ALKYL AND ARYL HALIDE-EXERCISE
  1. Match the following.

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  2. Match the following.

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  3. Math the following.

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  4. Statement-I: Iodination of akanes is carried out by heat in presence o...

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  5. Statement-I: Chloropropane has higher boiling point than chloroethane....

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  6. Statement-I: Polar solvent slows down S(N^(2)) reaction. Because Sta...

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  7. Statement-I:Primay benzylic halides are more reactive than primary alk...

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  8. Statement-I: Vinylic halides are reactive towards nucleophilic substit...

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  9. Statement-I: Aryl halidea undergo electrophilic substitution less radi...

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  10. Statement-I: Optically active 2-idoibutane on treatment with NaI in ac...

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  11. Statement-I: Free radical chlorination of n-butane gives 72% of 2-chlo...

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  12. Statement-I: Nucleophilic substitution reaction on an optically active...

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  13. Statement-I: Boiling point of alkyl halide increases with increases in...

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  14. An organic compound A has molecular formula C(10)H(17)Br and it is non...

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  15. An organic compound A has molecular formula C(10)H(17)Br and it is non...

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  16. An organic compound A has molecular formula C(10)H(17)Br and it is non...

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  17. An organic compound A has molecular formula C(10)H(17)Br and it is non...

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  18. Nucleophilic substitution reactions generally expressed as Nu^(-) +R...

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  19. Nucleophilic substitution reactions generally expressed as Nu^(-) +R...

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  20. Nucleophilic substitution reactions generally expressed as Nu^(-) +R...

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