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Statement-I: Aryl halidea undergo electr...

Statement-I: Aryl halidea undergo electrophilic substitution less radily than benzene.
Because Statement-II: Ary, halide gives only meta product w.r.t. electrophilic substitution.

A

Statement-I is True, Statement-II is True, Statement-II is a correct explanation for Statement-I

B

Statement-I is True, Statement-II is True, Statement-II is NOT a correct explanation for Statement-I

C

Statement-I is True, Statement-II is False.

D

Statement-I is False, Statement-II is True.

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the statements provided in the question, let's break down the reasoning step by step. ### Step 1: Understanding Aryl Halides and Electrophilic Substitution Aryl halides are compounds where a halogen atom is bonded to an aromatic ring. The process of electrophilic substitution involves an electrophile attacking the aromatic ring, replacing one of the hydrogen atoms. **Hint:** Recall the structure of aryl halides and how electrophilic substitution works in aromatic compounds. ### Step 2: Evaluating Statement I **Statement I:** "Aryl halides undergo electrophilic substitution less readily than benzene." - Aryl halides have a halogen substituent (like Cl, Br, I) which has both a -I (inductive) effect and a +R (resonance) effect. - The -I effect withdraws electron density from the ring, making it less reactive towards electrophiles compared to benzene, which has no such electron-withdrawing groups. - Therefore, this statement is **true**. **Hint:** Consider the effects of substituents on the reactivity of aromatic compounds. ### Step 3: Evaluating Statement II **Statement II:** "Aryl halides give only meta products with respect to electrophilic substitution." - The halogen substituent in aryl halides is an ortho/para directing group due to its +R effect, which stabilizes the carbocation intermediate formed during electrophilic substitution. - Therefore, aryl halides can yield ortho and para products, not just meta products. - This statement is **false**. **Hint:** Remember the directing effects of substituents in electrophilic aromatic substitution. ### Step 4: Conclusion - **Statement I is true**: Aryl halides undergo electrophilic substitution less readily than benzene. - **Statement II is false**: Aryl halides do not exclusively give meta products; they can give ortho and para products. Thus, the correct conclusion is that Statement I is true and Statement II is false. **Final Answer:** Statement I is true, Statement II is false.
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ALLEN-ALKYL AND ARYL HALIDE-EXERCISE
  1. Statement-I:Primay benzylic halides are more reactive than primary alk...

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  2. Statement-I: Vinylic halides are reactive towards nucleophilic substit...

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  3. Statement-I: Aryl halidea undergo electrophilic substitution less radi...

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  4. Statement-I: Optically active 2-idoibutane on treatment with NaI in ac...

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  5. Statement-I: Free radical chlorination of n-butane gives 72% of 2-chlo...

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  6. Statement-I: Nucleophilic substitution reaction on an optically active...

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  7. Statement-I: Boiling point of alkyl halide increases with increases in...

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  8. An organic compound A has molecular formula C(10)H(17)Br and it is non...

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  9. An organic compound A has molecular formula C(10)H(17)Br and it is non...

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  10. An organic compound A has molecular formula C(10)H(17)Br and it is non...

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  11. An organic compound A has molecular formula C(10)H(17)Br and it is non...

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  12. Nucleophilic substitution reactions generally expressed as Nu^(-) +R...

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  13. Nucleophilic substitution reactions generally expressed as Nu^(-) +R...

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  14. Nucleophilic substitution reactions generally expressed as Nu^(-) +R...

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  15. Nucleophilic substitution reactions generally expressed as Nu^(-) +R...

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  16. Nucleophilic aliphatic substitution reaction is mainly of two types: S...

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  17. Nucleophilic aliphatic substitution reaction is mainly of two types: S...

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  18. Nucleophilic aliphatic substitution reaction is mainly of two types: S...

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  19. An optically active compound A (assume dextrorotatory) has the molecul...

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  20. An optically active compound A (assume dextrorotatory) has the molecul...

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