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An organic compound A has molecular form...

An organic compound A has molecular formula `C_(10)H_(17)Br` and it is non-resolvable. A does not decolourize brown colour of bromine water solution. A on treatement with `(CH_(3))_(2 COK//(CH_(3))_(3)COH` yields `B` as majot product. B on treatment with `H_(2)//Pt` yields `(C_(10)H_(16))` which on treatment with `CI_(2)//hv` yields three monochloro derivative. Also B on boiling with acidic permanganate solution yields `C(C_(10)H_(16)O_(3))C`. on heating with sodalime yields `D(C_(9)H_(16)O).D` on reducing with `LiAIH_(4)` followed yields `C(C_(10)H_(16)O_(3)).C` on heating with sodalime yields `D(C_(9)H_(16)O).D` on reducing with `LiAIH_(4)` followed by heating product with concentrated `H_(2)SO_(4)` yields `E(C_(9)H_(16))` as major product. E on treatment with ozone followed by work-up with `Zn-H_(2)O` yields 6-Ketononanal.
Compound D is:

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
C
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ALLEN-ALKYL AND ARYL HALIDE-EXERCISE
  1. An organic compound A has molecular formula C(10)H(17)Br and it is non...

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  2. An organic compound A has molecular formula C(10)H(17)Br and it is non...

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  3. An organic compound A has molecular formula C(10)H(17)Br and it is non...

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  4. Nucleophilic substitution reactions generally expressed as Nu^(-) +R...

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  5. Nucleophilic substitution reactions generally expressed as Nu^(-) +R...

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  6. Nucleophilic substitution reactions generally expressed as Nu^(-) +R...

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  7. Nucleophilic substitution reactions generally expressed as Nu^(-) +R...

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  8. Nucleophilic aliphatic substitution reaction is mainly of two types: S...

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  9. Nucleophilic aliphatic substitution reaction is mainly of two types: S...

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  10. Nucleophilic aliphatic substitution reaction is mainly of two types: S...

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  11. An optically active compound A (assume dextrorotatory) has the molecul...

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  12. An optically active compound A (assume dextrorotatory) has the molecul...

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  13. Select the member of each pair that shows rate of S(N)2 reaction with ...

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  14. Of the following statements which are true for S(N)1 reaction. (a) T...

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  15. Of the following statements , which are true for S(N)2 reaction. (a)...

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  16. Arrange the isomers of molecular formula C(4)H(9)CI in order of decrea...

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  17. There is an overall 29-fold difference in reactivity of 1-chlorohexane...

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  18. Identify the product when A reacts with

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  19. Which is faster in the following pairs of halogen compounds undergoing...

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  20. R -Mg-Br(A) on reaction with H(2)O forms a gas (B), which occupied 1.4...

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