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During debromination of meso-2,3-dibromo...

During debromination of meso-2,3-dibromobutane, with `Zn` dust`//CH_(3)COOh` the major compound formed is-

A

n-butane

B

1-butane

C

cis-2-butane

D

trans-2-butane

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The correct Answer is:
To solve the question regarding the debromination of meso-2,3-dibromobutane with zinc dust in the presence of acetic acid (CH₃COOH), we can follow these steps: ### Step 1: Understand the Structure of Meso-2,3-Dibromobutane Meso-2,3-dibromobutane has the following structure: ``` Br Br | | CH₃-C-CH-CH₃ | | H H ``` This compound has two bromine atoms attached to the second and third carbon atoms of a butane chain. ### Step 2: Identify the Reaction Conditions The reaction is carried out using zinc dust (Zn) and acetic acid (CH₃COOH). Zinc is a reducing agent that will facilitate the removal of bromine atoms (debromination) from the molecule. ### Step 3: Mechanism of Debromination During debromination, the bromine atoms will be removed, and a double bond will be formed between the second and third carbon atoms. The reaction will result in the formation of an alkene. ### Step 4: Determine the Product Since meso-2,3-dibromobutane is a symmetrical molecule, the removal of the two bromine atoms can lead to the formation of a double bond in two possible configurations: cis or trans. However, the presence of zinc dust and acetic acid favors the formation of the cis product. The major product formed will be: ``` H H | | CH₃-C=C-CH₃ ``` This structure corresponds to **cis-2-butene**. ### Step 5: Conclusion The major compound formed during the debromination of meso-2,3-dibromobutane with zinc dust and acetic acid is **cis-2-butene**. ---
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ALLEN-ALKYL AND ARYL HALIDE-EXERCISE-05 (B)
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  2. Given the total number of isomers, including stereoisomers, obtained o...

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  3. During debromination of meso-2,3-dibromobutane, with Zn dust//CH(3)COO...

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  4. Benzyl chloride can be prepared from toluene by chlorination with

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  5. Toluene, when treated with Br(2)Fe, gives o and p-bromotoluene, becaus...

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  6. A solution of (+)2-chloro-2-phenylethane in toluene racemises slowly i...

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  7. The order of reactivities of the following alkyl halides for an S(N^2)...

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  8. Which of the following has the highest nucleophilicity ? F^(-) OH^...

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  9. An S(N)2 reaction at an asymmetric carbon of a compound always g...

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  10. The number of isomers possible for the molecular formula C(2) FCIBrl i...

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  11. In the presence of peroxide, hydrogen chloride and hydrogen iodide do ...

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  12. Identify the set of reagents // reaction conditions 'X' and 'Y' in the...

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  14. The reagent(s) for the following conversion is/are:

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  15. In the following groups: (I) -OAc, (II) -OMe, (III) -OSO(2)Me, (IV) ...

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  16. CH(3)CH(2)CHCl(2) overset(Aq.KOH)rarr?

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  17. Draw the stereochemical structure of the product in the following reac...

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  18. Given reasons:

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  19. An alkyl halide (A) of formula C(6)H(11)Cl on treatement with potassiu...

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  20. With would be the major product in each of the following reactions?

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