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The electrochemical cell shown below is a concentration cell. `M|M^(2+)(` saturated solution of sparingly soluble salt, `MX_(2))||M^(2+)(0.001 mol dm^(-3))|M`
The `emf` of the cell depends on the difference in the concentration of `M^(2+)` ions at the two electrodes. The `emf` of the cell at `298` is `0.059V`.
The solubility product `(K_(sp),mol^(3) dm^(-9))` of `MX_(2)` at 298 based on the information available the given concentration cell is `(` Take `2.303xxRxx298//F=0.059V)`

A

`-5.7`

B

`5.7`

C

`11.4`

D

`-11.4`

Text Solution

Verified by Experts

The correct Answer is:
D

`:' DeltaG =- nFE`
`DeltaG =- 2 xx 96500 xx 0.059` Joule
`=- 11.4` kJ/mole
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