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An aqueous solution of X is added slowly...

An aqueous solution of X is added slowly to an aqueous solution of Y as shown in List-I. The variation in conductivity of these reactions is given in List-II. Match List-I with List-II and select the correct answer using the code given below the lists:
`{:(List-I,List-II),((P)(C_(2)H_(5))_(3)N +CH_(3)COOH,(1)"Conductivity decreases adn then increases"),(" X Y",),((Q)KI(0.1M)+AgNO_(3)(0.01M),(2)"Conductivity decreases and then does not change much"),(" X Y",),((R)CH_(3)COOH+KOH,(3)"Conductivity increases and then does not change much"),(" X Y",),((S)NaOH+Hi,(4)"Conductivity does not change much and then increases"),(" X Y",):}`
Codes:

A

`{:(P,Q,R,S),(3,4,2,1):}`

B

`{:(P,Q,R,S),(4,3,2,1):}`

C

`{:(P,Q,R,S),(2,3,4,1):}`

D

`{:(P,Q,R,S),(1,4,3,2):}`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reactions and their effects on conductivity step by step. ### Step-by-Step Solution: 1. **Identify the Reactions**: - **P**: \( (C_2H_5)_3N + CH_3COOH \) - **Q**: \( KI(0.1M) + AgNO_3(0.01M) \) - **R**: \( CH_3COOH + KOH \) - **S**: \( NaOH + HI \) 2. **Analyze Reaction P**: - **Type**: Weak base (triethylamine) + weak acid (acetic acid). - **Conductivity**: Initially increases as ions are formed, but then levels off as the reaction reaches equilibrium. - **Match**: This corresponds to (3) "Conductivity increases and then does not change much". 3. **Analyze Reaction Q**: - **Type**: Strong electrolyte (KI) + strong electrolyte (AgNO3). - **Conductivity**: The conductivity does not change much initially as both are strong electrolytes, but then it increases as AgI precipitates out. - **Match**: This corresponds to (4) "Conductivity does not change much and then increases". 4. **Analyze Reaction R**: - **Type**: Weak acid (acetic acid) + strong base (KOH). - **Conductivity**: Initially decreases as the weak acid reacts with the strong base, but then levels off as the solution becomes neutralized. - **Match**: This corresponds to (2) "Conductivity decreases and then does not change much". 5. **Analyze Reaction S**: - **Type**: Strong base (NaOH) + strong acid (HI). - **Conductivity**: Initially decreases as the acid and base neutralize each other, but then increases as the solution becomes more ionic. - **Match**: This corresponds to (1) "Conductivity decreases and then increases". ### Final Matching: - **P** matches with (3) - **Q** matches with (4) - **R** matches with (2) - **S** matches with (1) ### Conclusion: The correct answer code is: - P - 3 - Q - 4 - R - 2 - S - 1

To solve the problem, we need to analyze the reactions and their effects on conductivity step by step. ### Step-by-Step Solution: 1. **Identify the Reactions**: - **P**: \( (C_2H_5)_3N + CH_3COOH \) - **Q**: \( KI(0.1M) + AgNO_3(0.01M) \) - **R**: \( CH_3COOH + KOH \) ...
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