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For an ideal solution containing a nonvo...

For an ideal solution containing a nonvolatile solute, which of the following expression represents the vapour pressure of the solute ? `(x_(1)rarr` mole fraction of solvent)

A

`p = x_(2) p_(2)`

B

`p = x_(1)p_(2)`

C

`p = x_(1)p_(1)`

D

`p_(1) - p = x_(2)`

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The correct Answer is:
To determine the expression that represents the vapor pressure of a solute in an ideal solution containing a non-volatile solute, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Components**: - In an ideal solution, we have a solvent and a non-volatile solute. The mole fraction of the solvent is denoted as \( x_1 \) and the mole fraction of the solute can be denoted as \( x_2 \). 2. **Vapor Pressure of Pure Solvent**: - The vapor pressure of the pure solvent is represented as \( P_0 \). This is the pressure exerted by the vapor of the solvent when it is in equilibrium with its liquid phase. 3. **Raoult's Law**: - According to Raoult's Law, the vapor pressure of the solvent in the solution is directly proportional to the mole fraction of the solvent. The law states: \[ P = x_1 \cdot P_0 \] - Here, \( P \) is the vapor pressure of the solution, \( x_1 \) is the mole fraction of the solvent, and \( P_0 \) is the vapor pressure of the pure solvent. 4. **Vapor Pressure of Solute**: - Since the solute is non-volatile, it does not contribute to the vapor pressure of the solution. Therefore, the vapor pressure of the solute itself is considered to be zero in this context. 5. **Final Expression**: - Thus, the expression that represents the vapor pressure of the solution containing a non-volatile solute is: \[ P = x_1 \cdot P_0 \] - This indicates that the vapor pressure of the solution depends on the mole fraction of the solvent and the vapor pressure of the pure solvent. ### Conclusion: The correct expression representing the vapor pressure of the solution containing a non-volatile solute is: \[ P = x_1 \cdot P_0 \]
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