Home
Class 12
CHEMISTRY
Statement-I: 0.02m solutions of urea and...

Statement-I: `0.02m` solutions of urea and sucrose will freeze at same temperature.
Because
Statement-II: Freezing point of a solution is inversely proportional to the conc. of solution.

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the statements given in the question, we need to break down the information provided and apply our understanding of colligative properties, specifically the freezing point depression. ### Step-by-Step Solution: 1. **Understanding the Statements**: - **Statement I**: "0.02m solutions of urea and sucrose will freeze at the same temperature." - **Statement II**: "Freezing point of a solution is inversely proportional to the concentration of the solution." 2. **Freezing Point Depression**: The freezing point depression (\( \Delta T_f \)) is given by the formula: \[ \Delta T_f = K_f \cdot m \] where \( K_f \) is the freezing point depression constant and \( m \) is the molality of the solution. 3. **Analyzing Statement I**: - For both urea and sucrose, we have the same molality of 0.02m. - Since both solutions have the same molality, the freezing point depression for both will be the same, assuming \( K_f \) values for both solutes are similar (which they are for dilute solutions). - Therefore, the freezing points of both solutions will indeed be the same. 4. **Conclusion for Statement I**: - Statement I is **True**. 5. **Analyzing Statement II**: - The freezing point depression is directly proportional to the molality of the solution, which means that as the concentration (molality) increases, the freezing point depression also increases. - This implies that the freezing point of the solution decreases as the concentration increases, indicating an inverse relationship between freezing point and concentration. - Therefore, Statement II is also **True**. 6. **Correct Explanation**: - While both statements are true, Statement II does not correctly explain Statement I. Statement I is true because both solutions have the same molality, not solely because of the inverse relationship mentioned in Statement II. 7. **Final Conclusion**: - Both statements are true, but Statement II is not the correct explanation for Statement I. ### Summary: - **Statement I**: True - **Statement II**: True - **Explanation**: Statement II is not the correct explanation for Statement I.
Promotional Banner

Topper's Solved these Questions

  • SOLUTIONS

    ALLEN|Exercise EXERCISE-04 [A]|17 Videos
  • SOLUTIONS

    ALLEN|Exercise EXERCISE-04 [B]|20 Videos
  • SOLUTIONS

    ALLEN|Exercise EXERCISE -02|44 Videos
  • S-BLOCK ELEMENTS

    ALLEN|Exercise EXERCISE -3|1 Videos
  • Some Basic Concepts of Chemistry (Mole concept)

    ALLEN|Exercise All Questions|39 Videos

Similar Questions

Explore conceptually related problems

Freezing point of solution is marked as

At freezing point of a solution there is always

The lowest freezing point of 0.1 M aqueous solution is of:

The freezing point of equimolal solution will be highest for :

The freezing point of solution is ……..than the boiling point of pure solvent.

Freezing point of a solution is smaller than freezing point of a solvent. It is due to :

Statement-I: If decimolal solution of sodium chloride boils at 101.2^(@)C , then decimolal solution of calcium chloride will also boil at the same temperature. Because Statement-II: For same molal concentration of aqueous solutions of electrolytes, the elevation of boiling point may not be same.

Which of the following aq. solutions will freeze at highest temperature?

Correct the following Statements by changing the underlined part of the sentence. (Do not change the whole sentence): ul("Freezing point") of a solution is directly proportional to its molality.

Depression in freezing point of solution of electrolytes are generally

ALLEN-SOLUTIONS-EXERCISE-03
  1. For a binary liquid solution of A and B. P^(overset(0)A)= pure vapour ...

    Text Solution

    |

  2. {:(Column-I,Column-II),("Colligative properties","Aqueous solution " (...

    Text Solution

    |

  3. Assertion (A): 0.1 M solution of NaCl has greater osmotic pressure tha...

    Text Solution

    |

  4. Statement-I: Relative lowering of vapour pressure is equal to mole fra...

    Text Solution

    |

  5. Statement-I : Molal elevation constant depends on the nature of solven...

    Text Solution

    |

  6. Statement-I: 0.02m solutions of urea and sucrose will freeze at same t...

    Text Solution

    |

  7. Statement-I: When mercuric iodide(s) is added to the aqueous solution ...

    Text Solution

    |

  8. Statement-I: 1M solution of Glauber's salt is isotonic with 1M solutio...

    Text Solution

    |

  9. Statement-I: If decimolal solution of sodium chloride boils at 101.2^(...

    Text Solution

    |

  10. Statement-1 : The freezing of water is an endothermic process. State...

    Text Solution

    |

  11. These questions consists of two statements each, printed as Statement-...

    Text Solution

    |

  12. Azoetropes are constant boiling mixtures, which like a pure chemical c...

    Text Solution

    |

  13. Azoetropes are constant boiling mixtures, which like a pure chemical c...

    Text Solution

    |

  14. Azoetropes are constant boiling mixtures, which like a pure chemical c...

    Text Solution

    |

  15. 10 mole of liquid 'A' and 20 mole of liquid 'B' is mixed in a cylindri...

    Text Solution

    |

  16. 10 mole of liquid 'A' and 20 mole of liquid 'B' is mixed in a cylindri...

    Text Solution

    |

  17. 10 mole of liquid 'A' and 20 mole of liquid 'B' is mixed in a cylindri...

    Text Solution

    |

  18. Acetic acid tends to form dimer due to formation of intermolcular hydr...

    Text Solution

    |

  19. Acetic acid tends to form dimer due to formation of intermolcular hydr...

    Text Solution

    |

  20. Acetic acid tends to form dimer due to formation of intermolcular hydr...

    Text Solution

    |