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An aqueous solution of a salt MX(2) at c...

An aqueous solution of a salt `MX_(2)` at certain temperature has a van'f Hoff factor of 2. The degree of dissociation for this solution of the salt is:

A

`0.50`

B

`0.80`

C

`0.67`

D

`0.33`

Text Solution

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The correct Answer is:
To find the degree of dissociation (α) for the aqueous solution of the salt \( MX_2 \) with a van 't Hoff factor (i) of 2, we can follow these steps: ### Step 1: Understand the dissociation of the salt The salt \( MX_2 \) dissociates in water to give: - 1 ion of \( M^{2+} \) - 2 ions of \( X^{-} \) Thus, the total number of ions produced (n) when one formula unit of \( MX_2 \) dissociates is: \[ n = 1 + 2 = 3 \] ### Step 2: Use the van 't Hoff factor The van 't Hoff factor (i) is related to the degree of dissociation (α) and the number of particles produced (n) by the formula: \[ i = 1 + (n - 1) \cdot \alpha \] ### Step 3: Substitute known values into the equation We know: - \( i = 2 \) - \( n = 3 \) Substituting these values into the equation: \[ 2 = 1 + (3 - 1) \cdot \alpha \] ### Step 4: Simplify the equation Now simplify the equation: \[ 2 = 1 + 2\alpha \] Subtract 1 from both sides: \[ 2 - 1 = 2\alpha \] \[ 1 = 2\alpha \] ### Step 5: Solve for α Now, divide both sides by 2: \[ \alpha = \frac{1}{2} \] Thus, the degree of dissociation (α) is: \[ \alpha = 0.5 \] ### Conclusion The degree of dissociation for the solution of the salt \( MX_2 \) is 0.5. ### Final Answer The correct choice for this question is option A: 0.50. ---
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