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Assertion : The pH of pure water is less...

Assertion : The `pH` of pure water is less than `7` at `60^(@)C`.
Reason : As the temperature increases, pure water becomes slightly acidic.

A

If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.

B

If both Assertion & Reason are True but Reason is not a correct explanation of the Assertiion.

C

If Assertion is True but the Reason is False.

D

If both Assertion & Reason are False

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The correct Answer is:
To solve the assertion and reason question, we need to analyze both statements carefully. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the pH of pure water is less than 7 at 60°C. - At 25°C (298 K), the pH of pure water is 7. As temperature increases, the ionic product of water (Kw) also increases. 2. **Calculating Kw at Different Temperatures**: - At 25°C (298 K), Kw = 10^(-14). - At 60°C, Kw increases to approximately 10^(-13). 3. **Determining pH at 60°C**: - The relationship between Kw and pH is given by the equation: \[ pH = -\log[H^+] \] - Since Kw = [H+][OH-] and at neutrality [H+] = [OH-], we can set [H+] = [OH-] = x. - Therefore, at 60°C: \[ Kw = x^2 = 10^{-13} \implies x = \sqrt{10^{-13}} = 10^{-6.5} \] - Thus, the pH at 60°C is: \[ pH = -\log(10^{-6.5}) = 6.5 \] - This shows that the pH of pure water at 60°C is indeed less than 7. 4. **Understanding the Reason**: - The reason states that as the temperature increases, pure water becomes slightly acidic. - While it is true that the pH decreases with increasing temperature, this does not mean that water becomes acidic in the traditional sense (where pH < 7 indicates acidity). 5. **Conclusion**: - The assertion is true: the pH of pure water is less than 7 at 60°C. - The reason is false: while the pH decreases, pure water remains neutral (the concentrations of [H+] and [OH-] are equal). ### Final Answer: - The assertion is true, but the reason is false.

To solve the assertion and reason question, we need to analyze both statements carefully. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the pH of pure water is less than 7 at 60°C. - At 25°C (298 K), the pH of pure water is 7. As temperature increases, the ionic product of water (Kw) also increases. ...
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