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The potential energy between two atoms i...

The potential energy between two atoms in a molecule is given by
`U=ax^(2)-bx^(2)`
where `a` and `b` are positive constants and `x` is the distance between the atoms. The atom is in stable equilibrium when `x` is equal to `:-`

A

`0`

B

`(2b)/(3a)`

C

`(3a)/(2b)`

D

`(3b)/(2a)`

Text Solution

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The correct Answer is:
To find the distance \( x \) at which the atom is in stable equilibrium, we start with the given potential energy equation: \[ U = ax^2 - bx^3 \] where \( a \) and \( b \) are positive constants. ### Step 1: Find the Force The force \( F \) acting between the atoms can be derived from the potential energy \( U \) using the relation: \[ F = -\frac{dU}{dx} \] ### Step 2: Differentiate the Potential Energy Now, we differentiate \( U \) with respect to \( x \): \[ \frac{dU}{dx} = \frac{d}{dx}(ax^2 - bx^3) = 2ax - 3bx^2 \] ### Step 3: Set the Force to Zero for Equilibrium For equilibrium, the force must be zero: \[ F = -\frac{dU}{dx} = 0 \implies 2ax - 3bx^2 = 0 \] ### Step 4: Factor the Equation We can factor out \( x \): \[ x(2a - 3bx) = 0 \] This gives us two solutions: 1. \( x = 0 \) 2. \( 2a - 3bx = 0 \) ### Step 5: Solve for \( x \) From the second equation, we can solve for \( x \): \[ 2a = 3bx \implies x = \frac{2a}{3b} \] ### Step 6: Check Stability To ensure that this point is a point of stable equilibrium, we need to check the second derivative of \( U \): \[ \frac{d^2U}{dx^2} = \frac{d}{dx}(2ax - 3bx^2) = 2a - 6bx \] Now, substituting \( x = \frac{2a}{3b} \): \[ \frac{d^2U}{dx^2} = 2a - 6b\left(\frac{2a}{3b}\right) = 2a - 4a = -2a \] Since \( a > 0 \), \( \frac{d^2U}{dx^2} < 0 \), indicating that the equilibrium is stable. ### Final Answer Thus, the distance \( x \) at which the atom is in stable equilibrium is: \[ x = \frac{2a}{3b} \]

To find the distance \( x \) at which the atom is in stable equilibrium, we start with the given potential energy equation: \[ U = ax^2 - bx^3 \] where \( a \) and \( b \) are positive constants. ...
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