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A solution required [OH^(-)]=2M. If degr...

A solution required `[OH^(-)]=2M`. If degree of dissociation of `Mg(OH)_(2)` is `alpha`, what analytical molarity solution of `Mg(OH)_(2)` is

A

`alpha`

B

`2alpha`

C

`1//alpha`

D

`1//2alpha`

Text Solution

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The correct Answer is:
To solve the problem, we need to determine the analytical molarity of a solution of magnesium hydroxide (Mg(OH)₂) that will provide a hydroxide ion concentration of 2 M, given that the degree of dissociation is α. ### Step-by-Step Solution: 1. **Write the dissociation equation for Mg(OH)₂:** \[ \text{Mg(OH)}_2 \rightleftharpoons \text{Mg}^{2+} + 2\text{OH}^- \] From this equation, we can see that one mole of magnesium hydroxide dissociates to produce one mole of magnesium ions and two moles of hydroxide ions. 2. **Let the initial concentration of Mg(OH)₂ be C (Molarity):** - Initially, before dissociation, the concentration of Mg(OH)₂ is C. 3. **Define the degree of dissociation (α):** - The degree of dissociation (α) is the fraction of the original substance that has dissociated. Therefore, at equilibrium: - The concentration of undissociated Mg(OH)₂ = \(C(1 - \alpha)\) - The concentration of Mg²⁺ ions = \(C\alpha\) - The concentration of OH⁻ ions = \(2C\alpha\) (since 2 moles of OH⁻ are produced for every mole of Mg(OH)₂ that dissociates). 4. **Set up the equation for hydroxide ion concentration:** - We know from the problem that the required concentration of OH⁻ ions is 2 M. \[ 2C\alpha = 2 \] 5. **Solve for C:** - Rearranging the equation gives: \[ C\alpha = 1 \] \[ C = \frac{1}{\alpha} \] 6. **Conclusion:** - Therefore, the analytical molarity of the Mg(OH)₂ solution required to achieve a hydroxide ion concentration of 2 M, given the degree of dissociation α, is: \[ C = \frac{1}{\alpha} \text{ M} \] ### Final Answer: The analytical molarity solution of Mg(OH)₂ is \( \frac{1}{\alpha} \) M. ---

To solve the problem, we need to determine the analytical molarity of a solution of magnesium hydroxide (Mg(OH)₂) that will provide a hydroxide ion concentration of 2 M, given that the degree of dissociation is α. ### Step-by-Step Solution: 1. **Write the dissociation equation for Mg(OH)₂:** \[ \text{Mg(OH)}_2 \rightleftharpoons \text{Mg}^{2+} + 2\text{OH}^- \] ...
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