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Assertion :- BaSO(4) forms white ppt in ...

Assertion `:-` `BaSO_(4)` forms white ppt in water.
Reason `:-` Its lattice energy is lower than its hydration energy.

A

If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.

B

If both Assertion & Reason are True but Reason is not a correct explanation of the Assertiion.

C

If Assertion is True but the Reason is False.

D

If both Assertion & Reason are False

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that "BaSO₄ forms a white precipitate in water." - **Analysis**: Barium sulfate (BaSO₄) is known to be insoluble in water. When BaSO₄ is added to water, it does not dissolve and instead forms a white precipitate. Therefore, the assertion is **true**. ### Step 2: Understand the Reason The reason states that "Its lattice energy is lower than its hydration energy." - **Analysis**: Lattice energy is the energy required to separate one mole of a solid ionic compound into its gaseous ions. Hydration energy is the energy released when gaseous ions are surrounded by water molecules. For BaSO₄, the lattice energy is actually **greater** than the hydration energy, which is why it does not dissolve in water. Therefore, the reason is **false**. ### Conclusion - The assertion is true (BaSO₄ does form a white precipitate in water). - The reason is false (the lattice energy of BaSO₄ is greater than its hydration energy, not lower). Thus, the correct answer is that the assertion is true, but the reason is false. ### Final Answer Assertion is true, but the reason is false. ---
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