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If the concentration of Y ^(-) ion in th...

If the concentration of` Y ^(-)` ion in the reaction
`XY_(3(s)) hArr X_(aq)^(+3)+3Y^(-)(aq)` is
decreased by `(1)/(2)` times, then equilibrium `conc^(n)` of
`X^(+3)` will increase by :-

A

2 times

B

4 times

C

8 times

D

16 times

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the equilibrium reaction and how the change in concentration of the `Y^(-)` ion affects the concentration of `X^(+3)` ion. ### Step-by-Step Solution: 1. **Write the Equilibrium Reaction**: The given reaction is: \[ XY_3(s) \rightleftharpoons X^{+3}(aq) + 3Y^{-}(aq) \] 2. **Write the Expression for Equilibrium Constant (Kc)**: The equilibrium constant expression for this reaction is given by: \[ K_c = \frac{[X^{+3}]}{[Y^{-}]^3} \] Here, `[X^{+3}]` is the concentration of `X^(+3)` ions and `[Y^{-}]` is the concentration of `Y^(-)` ions. 3. **Initial Concentration of Y^-**: Let the initial concentration of `Y^-` be `[Y^{-}] = Y_0`. 4. **Decrease Concentration of Y^-**: According to the problem, the concentration of `Y^-` is decreased by half: \[ [Y^{-}] = \frac{1}{2} Y_0 \] 5. **Substituting into the Kc Expression**: Now we substitute the new concentration of `Y^-` into the Kc expression: \[ K_c = \frac{[X^{+3}]}{(\frac{1}{2} Y_0)^3} \] Simplifying this gives: \[ K_c = \frac{[X^{+3}]}{\frac{1}{8} Y_0^3} = 8 \cdot \frac{[X^{+3}]}{Y_0^3} \] 6. **Setting the Two Kc Expressions Equal**: Let’s denote the initial concentration of `X^(+3)` as `[X^{+3}] = X_0`. Therefore, we have: \[ K_c = \frac{X_0}{Y_0^3} \] Setting the two expressions for `K_c` equal gives: \[ \frac{X_0}{Y_0^3} = 8 \cdot \frac{[X^{+3}]}{Y_0^3} \] 7. **Solving for New Concentration of X^(+3)**: Canceling out `Y_0^3` from both sides: \[ X_0 = 8 \cdot [X^{+3}] \] Therefore, the new concentration of `X^(+3)` can be expressed as: \[ [X^{+3}] = \frac{X_0}{8} \] 8. **Conclusion**: The equilibrium concentration of `X^(+3)` will increase by a factor of 8 when the concentration of `Y^(-)` is decreased by half. ### Final Answer: The equilibrium concentration of `X^(+3)` will increase by a factor of **8**.

To solve the problem, we need to analyze the equilibrium reaction and how the change in concentration of the `Y^(-)` ion affects the concentration of `X^(+3)` ion. ### Step-by-Step Solution: 1. **Write the Equilibrium Reaction**: The given reaction is: \[ XY_3(s) \rightleftharpoons X^{+3}(aq) + 3Y^{-}(aq) ...
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