Home
Class 12
CHEMISTRY
In the hydrolysis equilibrium B^(+)+H(...

In the hydrolysis equilibrium
`B^(+)+H_(2)OhArrBOH+H^(+),K_(b)=1xx10^(-5)`
The hydrolysis constant is

A

`10^(-5)`

B

`10^(-19)`

C

`10^(-10)`

D

`10^(-9)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the hydrolysis constant (K_h) for the given equilibrium reaction: \[ B^+ + H_2O \rightleftharpoons BOH + H^+ \] with the provided base dissociation constant \( K_b = 1 \times 10^{-5} \), we can follow these steps: ### Step 1: Understand the relationship between K_h and K_b The hydrolysis constant \( K_h \) can be calculated using the relationship: \[ K_h = \frac{K_w}{K_b} \] where \( K_w \) is the ion product of water, which is typically \( 1 \times 10^{-14} \) at 25°C. ### Step 2: Substitute the known values into the equation We know: - \( K_w = 1 \times 10^{-14} \) - \( K_b = 1 \times 10^{-5} \) Substituting these values into the equation gives: \[ K_h = \frac{1 \times 10^{-14}}{1 \times 10^{-5}} \] ### Step 3: Perform the calculation Now, we simplify the expression: \[ K_h = 1 \times 10^{-14} \div 1 \times 10^{-5} = 1 \times 10^{-14 + 5} = 1 \times 10^{-9} \] ### Step 4: State the final answer Thus, the hydrolysis constant \( K_h \) is: \[ K_h = 1 \times 10^{-9} \] ### Final Answer The hydrolysis constant is \( 1 \times 10^{-9} \). ---

To find the hydrolysis constant (K_h) for the given equilibrium reaction: \[ B^+ + H_2O \rightleftharpoons BOH + H^+ \] with the provided base dissociation constant \( K_b = 1 \times 10^{-5} \), we can follow these steps: ### Step 1: Understand the relationship between K_h and K_b The hydrolysis constant \( K_h \) can be calculated using the relationship: ...
Promotional Banner

Topper's Solved these Questions

  • CHEMISTRY AT A GLANCE

    ALLEN|Exercise INORGANIC CHEMISTRY|300 Videos
  • CHEMISTRY AT A GLANCE

    ALLEN|Exercise ORGANIC CHEMISTRY|472 Videos
  • Chemical Equilibrium

    ALLEN|Exercise All Questions|30 Videos
  • ELECTROCHEMISTRY

    ALLEN|Exercise EXERCISE -05 [B]|38 Videos

Similar Questions

Explore conceptually related problems

If the K_b value in the hydrolysis reaction B^(+)+H_2O hArr BOH +H^+ is 1.0 xx 10^(-6) , then the hydrolysis constant of the salt would be

In the equilibrium A^(-)+ H_(2)O hArr HA + OH^(-) (K_(a) = 1.0 xx 10^(-4)) . The degree of hydrolysis of 0.01 M solution of the salt is

Hydrolysis is an acid-basedreaction of a cation or anion or both ions of a salt with water, Resultan solution of hydrolysis may be acidic, basic or netural. The anion A^(-) which is a weakeer base than OH^(-) and which his its conjugate acid HA stronger then water but weaker than H_(3)O shown the phenomenon of hydrolysis Ex : CH_(3)COO^(-),CN^(-),NO_(2)^(-) etc. The contion B^(+) which is a weaker acid than H_(3)^(+) which is a weaker acid then H_(3)^(+) and which has its conjugate base BOH stronger than water but weak than OH^(-) shown the phenmenon of hydrolysis Ex : NH_(4)^(+)C_(6)H_(5)NH^(+),N_(2)H_(5)^(+) etc. The hydrolysis constant of anion and cation are given by A^(-)(aq.)+H_(2)O(l)hArrHA(aq.)+OH^(-)(aq) " " K_(h)=(K_(w))/(K_(a))rArr([HA(aq.)][OH^(-)(aq.)])/([A^(-)(aq.)]) B^(+)(aq.)+H_(2)O(l)hArrBOH(aq.)+H^(+)(aq.) " " K_(h)=(K_(w))/(K_(b))rArr([BOH(aq.)][H^(+)(aq.)])/([B^(-)(aq.)]) Calculate percentage degreeof hydrolysis in a 0.1 M solution of CH_(3)COONa.(K_(a)"of"CH_(3)COOH=10^(-5))

Hydrolysis is an acid-basedreaction of a cation or anion or both ions of a salt with water, Resultan solution of hydrolysis may be acidic, basic or netural. The anion A^(-) which is a weakeer base than OH^(-) and which his its conjugate acid HA stronger then water but weaker than H_(3)O shown the phenomenon of hydrolysis Ex : CH_(3)COO^(-),CN^(-),NO_(2)^(-) etc. The contion B^(+) which is a weaker acid than H_(3)^(+) which is a weaker acid then H_(3)^(+) and which has its conjugate base BOH stronger than water but weak than OH^(-) shown the phenmenon of hydrolysis Ex : NH_(4)^(+)C_(6)H_(5)NH^(+),N_(2)H_(5)^(+) etc. The hydrolysis constant of anion and cation are given by A^(-)(aq.)+H_(2)O(l)hArrHA(aq.)+OH^(-)(aq) " " K_(h)=(K_(w))/(K_(a))rArr([HA(aq.)][OH^(-)(aq.)])/([A^(-)(aq.)]) B^(+)(aq.)+H_(2)O(l)hArrBOH(aq.)+H^(+)(aq.) " " K_(h)=(K_(w))/(K_(b))rArr([BOH(aq.)][H^(+)(aq.)])/([B^(-)(aq.)]) When pure ammonium chloride is dissolved in pure water, the pH of the resulting not 7. This is because :

Hydrolysis is an acid-basedreaction of a cation or anion or both ions of a salt with water, Resultan solution of hydrolysis may be acidic, basic or netural. The anion A^(-) which is a weakeer base than OH^(-) and which his its conjugate acid HA stronger then water but weaker than H_(3)O shown the phenomenon of hydrolysis Ex : CH_(3)COO^(-),CN^(-),NO_(2)^(-) etc. The contion B^(+) which is a weaker acid than H_(3)^(+) which is a weaker acid then H_(3)^(+) and which has its conjugate base BOH stronger than water but weak than OH^(-) shown the phenmenon of hydrolysis Ex : NH_(4)^(+)C_(6)H_(5)NH^(+),N_(2)H_(5)^(+) etc. The hydrolysis constant of anion and cation are given by A^(-)(aq.)+H_(2)O(l)hArrHA(aq.)+OH^(-)(aq) " " K_(h)=(K_(w))/(K_(a))rArr([HA(aq.)][OH^(-)(aq.)])/([A^(-)(aq.)]) B^(+)(aq.)+H_(2)O(l)hArrBOH(aq.)+H^(+)(aq.) " " K_(h)=(K_(w))/(K_(b))rArr([BOH(aq.)][H^(+)(aq.)])/([B^(-)(aq.)]) Which of the following statement is true

Hydrolysis is an acid-basedreaction of a cation or anion or both ions of a salt with water, Resultan solution of hydrolysis may be acidic, basic or netural. The anion A^(-) which is a weakeer base than OH^(-) and which his its conjugate acid HA stronger then water but weaker than H_(3)O shown the phenomenon of hydrolysis Ex : CH_(3)COO^(-),CN^(-),NO_(2)^(-) etc. The contion B^(+) which is a weaker acid than H_(3)^(+) which is a weaker acid then H_(3)^(+) and which has its conjugate base BOH stronger than water but weak than OH^(-) shown the phenmenon of hydrolysis Ex : NH_(4)^(+)C_(6)H_(5)NH^(+),N_(2)H_(5)^(+) etc. The hydrolysis constant of anion and cation are given by A^(-)(aq.)+H_(2)O(l)hArrHA(aq.)+OH^(-)(aq) " " K_(h)=(K_(w))/(K_(a))rArr([HA(aq.)][OH^(-)(aq.)])/([A^(-)(aq.)]) B^(+)(aq.)+H_(2)O(l)hArrBOH(aq.)+H^(+)(aq.) " " K_(h)=(K_(w))/(K_(b))rArr([BOH(aq.)][H^(+)(aq.)])/([B^(-)(aq.)]) select the correct statement :

For the following equilibrium NH_(3)+H_(2)O hArr NH_(4)^(+)+OH^(-) calculate the equilibrium constant, if for the equilibrium, NH_(4)^(+)+H_(2)OhArr NH_(4)OH+H^(+) the equilibrium constant is 5.5xx10^(-10)

The degree of hydrolysis in hydrolytic equilibrium A^(-) + H_(2)O to HA + OH^(-) at salt concentration of 0.001 M is : (K_(a)=1xx10^(-5))

0.1 M solution of a salt of a weak acid a strong base hydrolysis. If K_(a) of the weak acid is 1 xx 10^(-5) , the percent hydrolysis of the salt is

What is the pH of 1MNaPO_(4) solution at 25^(@)C ? PO_(4)^(3-)+H_(2)OhArrHPO_(4)^(2-)+OH^(-),K_(b)=2.4xx10^(-2) Assume no hydrolysis of HPO_(4)^(2-) ions.