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The value of vander waal's constant a an...

The value of vander waal's constant a and b for two gases X and
Y are 4.6,0.04 (for X) and 5.1, 0.06 (for Y). Which can be
liquified easily an appolication of pressure :-

A

X

B

Y

C

Both 1 & 2

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine which gas, X or Y, can be liquefied more easily when pressure is applied, we will analyze the Van der Waals constants A and B for both gases. ### Step-by-Step Solution: 1. **Understand Van der Waals Constants:** - The Van der Waals constant \( a \) represents the strength of intermolecular forces. A lower value of \( a \) indicates weaker intermolecular forces, making it easier to liquefy the gas. - The Van der Waals constant \( b \) represents the effective size of gas molecules. A lower value of \( b \) indicates that the molecules occupy less volume, which also facilitates liquefaction. 2. **Given Values:** - For gas X: - \( a_X = 4.6 \) - \( b_X = 0.04 \) - For gas Y: - \( a_Y = 5.1 \) - \( b_Y = 0.06 \) 3. **Compare the Values of A:** - Compare \( a_X \) and \( a_Y \): - \( a_X (4.6) < a_Y (5.1) \) - This indicates that gas X has weaker intermolecular forces compared to gas Y. 4. **Compare the Values of B:** - Compare \( b_X \) and \( b_Y \): - \( b_X (0.04) < b_Y (0.06) \) - This indicates that gas X occupies less volume per molecule compared to gas Y. 5. **Conclusion:** - Since both \( a_X < a_Y \) and \( b_X < b_Y \), gas X has both weaker intermolecular forces and a smaller effective size. Therefore, gas X can be liquefied more easily than gas Y when pressure is applied. ### Final Answer: Gas X can be liquefied more easily than gas Y.
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