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Van't Hoff factor is 1.92 for MgI(2) sol...

Van't Hoff factor is 1.92 for `MgI_(2)` solution with concentraition 0.2M then the degree of dissociation of salt at this concentration is :-

A

`46%`

B

`96%`

C

`30.67%`

D

`64%`

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To solve the problem, we need to find the degree of dissociation (α) of magnesium iodide (MgI₂) in a solution where the Van't Hoff factor (i) is given as 1.92 and the concentration is 0.2 M. ### Step-by-Step Solution: 1. **Understanding the Dissociation of MgI₂:** Magnesium iodide dissociates in solution as follows: \[ \text{MgI}_2 \rightarrow \text{Mg}^{2+} + 2 \text{I}^- \] From this dissociation, we can see that one formula unit of MgI₂ produces one magnesium ion (Mg²⁺) and two iodide ions (I⁻), resulting in a total of three particles. 2. **Identifying the Van't Hoff Factor (i):** The Van't Hoff factor (i) is defined as the ratio of the actual number of particles in solution after dissociation to the number of formula units initially dissolved. For MgI₂, the expected value of i (if fully dissociated) would be 3 (1 Mg²⁺ + 2 I⁻). 3. **Calculating the Degree of Dissociation (α):** The degree of dissociation (α) can be calculated using the formula: \[ i = 1 + \frac{n - 1}{n} \cdot \alpha \] Where: - \(i\) = Van't Hoff factor (1.92) - \(n\) = number of particles expected from one formula unit of MgI₂ (which is 3) Rearranging the formula gives us: \[ \alpha = \frac{i - 1}{n - 1} \] 4. **Substituting the Values:** Now substituting the known values into the equation: \[ \alpha = \frac{1.92 - 1}{3 - 1} = \frac{0.92}{2} = 0.46 \] 5. **Converting to Percentage:** To express the degree of dissociation as a percentage, we multiply by 100: \[ \text{Degree of dissociation} = 0.46 \times 100 = 46\% \] ### Final Answer: The degree of dissociation of MgI₂ at a concentration of 0.2 M is **46%**.

To solve the problem, we need to find the degree of dissociation (α) of magnesium iodide (MgI₂) in a solution where the Van't Hoff factor (i) is given as 1.92 and the concentration is 0.2 M. ### Step-by-Step Solution: 1. **Understanding the Dissociation of MgI₂:** Magnesium iodide dissociates in solution as follows: \[ \text{MgI}_2 \rightarrow \text{Mg}^{2+} + 2 \text{I}^- ...
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