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K is rate constant at temp T then value ...

K is rate constant at temp T then value of `underset(Ttooo)lim` log K is equal to :-

A

`A//2.303`

B

A

C

2.303 A

D

log A

Text Solution

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The correct Answer is:
To solve the problem, we need to analyze the relationship between the rate constant \( K \) and the temperature \( T \) using the Arrhenius equation. The Arrhenius equation is given by: \[ K = A e^{-\frac{E_a}{RT}} \] Taking the logarithm of both sides, we have: \[ \log K = \log A - \frac{E_a}{2.303RT} \] Now, we need to evaluate the limit as \( T \) approaches infinity: \[ \lim_{T \to \infty} \log K \] Substituting the expression for \( \log K \): \[ \lim_{T \to \infty} \log K = \lim_{T \to \infty} \left( \log A - \frac{E_a}{2.303RT} \right) \] Now, we can separate the limit: \[ \lim_{T \to \infty} \log K = \lim_{T \to \infty} \log A - \lim_{T \to \infty} \frac{E_a}{2.303RT} \] Since \( \log A \) is a constant, its limit as \( T \) approaches infinity remains \( \log A \): \[ \lim_{T \to \infty} \log A = \log A \] Next, we analyze the second term: \[ \lim_{T \to \infty} \frac{E_a}{2.303RT} \] As \( T \) approaches infinity, \( \frac{1}{T} \) approaches \( 0 \). Therefore: \[ \lim_{T \to \infty} \frac{E_a}{2.303RT} = 0 \] Putting it all together, we have: \[ \lim_{T \to \infty} \log K = \log A - 0 = \log A \] Thus, the final result is: \[ \lim_{T \to \infty} \log K = \log A \] ### Final Answer: \[ \lim_{T \to \infty} \log K = \log A \]

To solve the problem, we need to analyze the relationship between the rate constant \( K \) and the temperature \( T \) using the Arrhenius equation. The Arrhenius equation is given by: \[ K = A e^{-\frac{E_a}{RT}} \] Taking the logarithm of both sides, we have: ...
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