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The reaction 2A+Bto product follow the m...

The reaction `2A+Bto` product follow the mechanism :-
`2AhArrA_(2)("fast")`
`A_(2)+BtoP(slow)`
`The order of the reaction is

A

1.5

B

3

C

1

D

2

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of the reaction given the mechanism, we can follow these steps: ### Step 1: Identify the Rate-Determining Step The mechanism provided indicates that the second step (A2 + B → P) is the slow step, which means it is the rate-determining step. The rate law for the overall reaction will be based on this step. ### Step 2: Write the Rate Law for the Slow Step For the slow step, the rate law can be expressed as: \[ \text{Rate} = k [A_2][B] \] where \( k \) is the rate constant, \( [A_2] \) is the concentration of \( A_2 \), and \( [B] \) is the concentration of \( B \). ### Step 3: Express \( [A_2] \) in Terms of \( [A] \) From the first step of the mechanism (2A ⇌ A2), we can derive the equilibrium expression. At equilibrium, we have: \[ K_{eq} = \frac{[A_2]}{[A]^2} \] Thus, we can express \( [A_2] \) as: \[ [A_2] = K_{eq} [A]^2 \] where \( K_{eq} \) is the equilibrium constant for the first step. ### Step 4: Substitute \( [A_2] \) into the Rate Law Now, we substitute \( [A_2] \) back into the rate law: \[ \text{Rate} = k [A_2][B] = k (K_{eq} [A]^2)[B] \] This simplifies to: \[ \text{Rate} = k K_{eq} [A]^2 [B] \] ### Step 5: Determine the Overall Order of the Reaction In the rate law \( \text{Rate} = k K_{eq} [A]^2 [B] \), the order of the reaction is determined by the sum of the powers of the concentrations: - The power of \( [A] \) is 2. - The power of \( [B] \) is 1. Thus, the overall order of the reaction is: \[ 2 + 1 = 3 \] ### Final Answer The order of the reaction is **3**. ---

To determine the order of the reaction given the mechanism, we can follow these steps: ### Step 1: Identify the Rate-Determining Step The mechanism provided indicates that the second step (A2 + B → P) is the slow step, which means it is the rate-determining step. The rate law for the overall reaction will be based on this step. ### Step 2: Write the Rate Law for the Slow Step For the slow step, the rate law can be expressed as: \[ \text{Rate} = k [A_2][B] \] ...
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