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When electrolysis of silver nitrate solu...

When electrolysis of silver nitrate solution is carried out using silver electrodes, wich of the following reaction occurs at the anode?

A

`Ag toAg^(+)+e^(-)`

B

`Ag^(+)+e^(-)toAg`

C

`2H_(2)Oto4H^(+)+O_(2)+4e^(-)`

D

`4OH^(-)to2H_(2)+O_(2)+4e^(-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the reaction that occurs at the anode during the electrolysis of silver nitrate solution using silver electrodes, we can follow these steps: ### Step 1: Understand the Electrolysis Process Electrolysis involves the breakdown of a compound in solution by passing an electric current through it. In this case, we are dealing with silver nitrate (AgNO₃) solution. ### Step 2: Identify the Components in the Solution When silver nitrate is dissolved in water, it dissociates into silver ions (Ag⁺) and nitrate ions (NO₃⁻). Therefore, the solution contains Ag⁺ and NO₃⁻ ions. ### Step 3: Determine the Anode Reaction At the anode, oxidation occurs. This means that a substance loses electrons. Since we are using silver electrodes, silver (Ag) will undergo oxidation. ### Step 4: Write the Oxidation Reaction The oxidation reaction at the anode can be represented as: \[ \text{Ag (s)} \rightarrow \text{Ag}^+ (aq) + e^- \] This equation shows that solid silver (Ag) loses one electron (e⁻) to become silver ions (Ag⁺). ### Step 5: Conclusion Thus, the reaction that occurs at the anode during the electrolysis of silver nitrate solution using silver electrodes is: \[ \text{Ag (s)} \rightarrow \text{Ag}^+ (aq) + e^- \]
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