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Select correct order out of given option...

Select correct order out of given options :-

A

`BeCO_(3)ltBaCO_(3)to` Covalent character

B

`BeOgtSrOto` Lattice anergy

C

`Be^(2+)ltLi^(+)to` Hydration energy

D

`Be_((aq.))^(2+)gtLi_((aq.))^(+)to` Ionic Mobility

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the correct order of properties among the given options, we will analyze each option step by step. ### Step 1: Analyze Option A **Statement:** Beryllium carbonate (BeCO3) has less covalent character than barium carbonate (BaCO3). **Analysis:** - As we move down Group 2 in the periodic table, the ionic character of the compounds generally increases due to the increase in atomic size. - Beryllium (Be) is smaller and has a higher charge density compared to barium (Ba), which leads to more covalent character in BeCO3 than in BaCO3. - Therefore, this statement is **false**. ### Step 2: Analyze Option B **Statement:** Beryllium oxide (BeO) has a higher lattice energy than strontium oxide (SrO). **Analysis:** - Lattice energy is influenced by the size of the ions; smaller ions lead to higher lattice energy due to stronger electrostatic forces. - Beryllium is smaller than strontium, and thus BeO will have a higher lattice energy compared to SrO. - Therefore, this statement is **true**. ### Step 3: Analyze Option C **Statement:** Hydration energy of Be2+ is less than that of Li+. **Analysis:** - Hydration energy is influenced by the charge and size of the ion. Beryllium (Be2+) has a higher effective nuclear charge than lithium (Li+), leading to a stronger attraction of water molecules. - Therefore, Be2+ has a higher hydration energy than Li+, making this statement **false**. ### Step 4: Analyze Option D **Statement:** Ionic mobility of Be2+ is more than that of Li+. **Analysis:** - Ionic mobility is inversely related to the size of the ion and its hydration energy. Since Be2+ is smaller and has a higher hydration energy, it will be more surrounded by water molecules and thus less mobile compared to Li+. - Therefore, this statement is **false**. ### Conclusion From the analysis: - Option A: False - Option B: True - Option C: False - Option D: False Thus, the correct order is given by **Option B**.
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