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Match the column Compound Shape {:((...

Match the column
Compound Shape
`{:((a)XeO_(2)F_(2),,,,(P)"Linear"),((b)XeF_(5)^(-),,,,(Q)"Square planar"),((c )I_(3)^(-),,,,(R)"See-saw"),((d)XeF_(4),,,,(S)"Pentagonal planar"):}`

A

(a)R (b)S (c )P (d)Q

B

(a)R (b)S (c )Q (d)P

C

(a)P (b)S ( c)Q (d)R

D

(a)S (b)Q ( c)P (d)R

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of matching the compounds with their respective shapes, we will analyze each compound one by one based on their molecular geometry. ### Step-by-Step Solution: 1. **Identify the shape of XeO₂F₂:** - The compound XeO₂F₂ has two oxygen atoms and two fluorine atoms attached to the central xenon atom. - The molecular geometry can be determined by considering the lone pairs and the arrangement of the bonded atoms. - XeO₂F₂ has a trigonal bipyramidal arrangement, but due to the presence of lone pairs, the shape is distorted to a **C-shaped (or seesaw)** structure. - **Match:** (a) XeO₂F₂ → (R) "C-shaped" 2. **Identify the shape of XeF₅⁻:** - For XeF₅⁻, there are five fluorine atoms bonded to xenon with a negative charge. - The geometry is based on a pentagonal bipyramidal arrangement, and since it has a negative charge, it adopts a **pentagonal planar** shape. - **Match:** (b) XeF₅⁻ → (S) "Pentagonal planar" 3. **Identify the shape of I₃⁻:** - The I₃⁻ ion consists of three iodine atoms with two lone pairs on the central iodine atom. - The arrangement of these atoms leads to a **linear** shape. - **Match:** (c) I₃⁻ → (P) "Linear" 4. **Identify the shape of XeF₄:** - In XeF₄, there are four fluorine atoms bonded to xenon and two lone pairs on the xenon atom. - The molecular geometry is square planar due to the arrangement of the fluorine atoms around the xenon. - **Match:** (d) XeF₄ → (Q) "Square planar" ### Final Matches: - (a) XeO₂F₂ → (R) "C-shaped" - (b) XeF₅⁻ → (S) "Pentagonal planar" - (c) I₃⁻ → (P) "Linear" - (d) XeF₄ → (Q) "Square planar" ### Summary of Matches: - A: R - B: S - C: P - D: Q
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