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The value of n in the carbonyl is [(CO...

The value of n in the carbonyl is
`[(CO)_(n)-Co-Co-(CO)_(n)]`

A

4

B

5

C

6

D

8

Text Solution

AI Generated Solution

The correct Answer is:
To find the value of \( n \) in the carbonyl compound represented as \([(CO)_{n}-Co-Co-(CO)_{n}]\), we will use the concept of effective atomic number (EAN). The steps are as follows: ### Step 1: Identify the Atomic Number of Cobalt Cobalt (Co) has an atomic number of 27. ### Step 2: Determine the Nearest Noble Gas Atomic Number The nearest noble gas to cobalt is Argon (Ar), which has an atomic number of 36. ### Step 3: Write the Effective Atomic Number Formula The formula for the effective atomic number (EAN) is given by: \[ \text{EAN} = \text{Atomic Number} - \text{Oxidation State} + \text{Electrons Gained by Coordination} \] ### Step 4: Identify the Oxidation State In the carbonyl complex, cobalt is in the zero oxidation state because carbonyl ligands (CO) are neutral. Therefore, the oxidation state is 0. ### Step 5: Substitute Known Values into the EAN Formula Substituting the known values into the EAN formula: \[ 36 = 27 - 0 + \text{Electrons from CO} \] ### Step 6: Calculate Electrons Gained from CO Each CO ligand donates 2 electrons. Since there are \( n \) CO ligands, the total contribution from CO ligands is \( 2n \) electrons. Thus, we can rewrite the equation as: \[ 36 = 27 + 2n \] ### Step 7: Solve for \( n \) Rearranging the equation gives: \[ 36 - 27 = 2n \] \[ 9 = 2n \] \[ n = \frac{9}{2} = 4.5 \] ### Step 8: Round \( n \) to the Nearest Whole Number Since \( n \) must be a whole number in this context, we round \( n \) to the nearest whole number, which is 4. ### Conclusion Thus, the value of \( n \) in the carbonyl complex \([(CO)_{n}-Co-Co-(CO)_{n}]\) is: \[ \boxed{4} \] ---

To find the value of \( n \) in the carbonyl compound represented as \([(CO)_{n}-Co-Co-(CO)_{n}]\), we will use the concept of effective atomic number (EAN). The steps are as follows: ### Step 1: Identify the Atomic Number of Cobalt Cobalt (Co) has an atomic number of 27. ### Step 2: Determine the Nearest Noble Gas Atomic Number The nearest noble gas to cobalt is Argon (Ar), which has an atomic number of 36. ...
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ALLEN-CHEMISTRY AT A GLANCE-INORGANIC CHEMISTRY
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