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Which of the following can exhibit tauto...

Which of the following can exhibit tautomerism:

A

B

C

D

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The correct Answer is:
To determine which of the given options can exhibit tautomerism, we need to analyze the structures provided in each option. Tautomerism typically involves the migration of a hydrogen atom and a shift of a double bond, often resulting in a keto-enol tautomeric relationship. ### Step-by-Step Solution: 1. **Identify the Structures**: - Write down the structures for each option provided in the question. 2. **Analyze Each Structure for Tautomerism**: - **Option A**: - Identify the alpha carbon and the presence of a carbonyl group (C=O). - Check if there are any alpha hydrogens that can migrate to the carbonyl carbon. - In this case, the presence of a bicyclic structure creates strain when attempting to form an enol, making it unstable. Therefore, tautomerism is not favorable. - **Option B**: - Similar analysis as in Option A. - Identify the alpha hydrogens and the carbonyl group. - Here, the structure allows for the migration of an alpha hydrogen to the carbonyl carbon without significant strain, making it more stable and capable of tautomerism. - **Option C**: - Again, identify the alpha hydrogens and carbonyl group. - The presence of conjugated double bonds in a cyclic structure prevents the formation of an enol form. Thus, tautomerism is not possible. - **Option D**: - Analyze the structure for alpha hydrogens and carbonyl group. - Similar to Option C, the cyclic structure with double bonds does not allow for the formation of an enol form, so tautomerism is not feasible. 3. **Conclusion**: - After analyzing all options, only **Option B** allows for the formation of an enol form due to the absence of significant strain and the presence of alpha hydrogens that can migrate to the carbonyl carbon. ### Final Answer: The only structure that can exhibit tautomerism is **Option B**.
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