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Correct order of stability of the follow...

Correct order of stability of the following resonating structure is
`CH_(2)=underset((a))(CH)-overset(O)overset(||)C-Hharroverset(Theta)(C)H_(2)-underset((b))(CH)=overset(Theta)overset(O)overset(|)(C)-Hharroverset(Theta)overset(* *)(C)H_(2)-underset((c ))(CH)=overset(o+)overset(O)overset(|)(C)-H`

A

`agtbgtc`

B

`agtcgtb`

C

`bgtagtc`

D

`cgtbgta`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of stability of the given resonating structures, we will follow the stability criteria for resonance structures. Here’s a step-by-step breakdown of the solution: ### Step 1: Identify the Resonating Structures We have three resonating structures labeled as A, B, and C. We need to analyze each structure based on the stability criteria. ### Step 2: Apply Stability Criteria 1. **Charge-less Species**: Resonating structures without charges are generally more stable than those with charges. 2. **Charge Distribution**: If charges are present, the stability is determined by the location of the charges: - A positive charge should be on an electropositive atom. - A negative charge should be on an electronegative atom. 3. **Electronegativity Consideration**: Atoms like oxygen are electronegative and do not stabilize positive charges well. ### Step 3: Analyze Each Structure - **Structure A**: This structure is charge-less. According to our criteria, it is highly stable. - **Structure B**: This structure has a positive charge on oxygen. Since oxygen is electronegative, it cannot stabilize a positive charge effectively, making this structure less stable. - **Structure C**: This structure has a negative charge on a carbon atom. While it has a charge, carbon can tolerate a negative charge better than oxygen can tolerate a positive charge. However, it is still less stable than a charge-less structure. ### Step 4: Order the Stability Based on our analysis: - **Most Stable**: Structure A (charge-less) - **Moderately Stable**: Structure C (negative charge on carbon) - **Least Stable**: Structure B (positive charge on oxygen) Thus, the correct order of stability is: **A > C > B** ### Final Answer The correct order of stability of the resonating structures is A, C, B. ---
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The order of stability of the following tautomeric compounds is (i). CH_(2)=overset(OH)overset(|)(CH)-CH_(2)-overset(O)overset(||)(C)-CH_(3)hArr (ii). CH_(3)-overset(O)overset(||)(C)-CH_(2)-overset(O)overset(||)(C)-CH_(3)hArr (iii). CH_(3)-overset(OH)overset(|)(C)=CH-overset(O)overset(||)(C)-CH_(3)

The order of stability of the following tautomeric compounds is (i). CH_(2)=overset(OH)overset(|)(CH)-CH_(2)-overset(O)overset(||)(C)-CH_(3)hArr (ii). CH_(3)-overset(O)overset(||)(C)-CH_(2)-overset(O)overset(||)(C)-CH_(3)hArr (iii). CH_(3)-overset(OH)overset(|)(C)=CH-overset(O)overset(||)(C)-CH_(3)

For the given four structures , I to IV, which of the following is correct ? underset((I))(C_(2)H_(5)-overset(CH_(3))overset(|)(C)H-C_(3)H_(7)) underset((II))(CH_(3)-overset(O)overset(P)(C)-overset(CH_(3))overset(|)(C)H-C_(2)H_(5)) underset((III))(CH_(3)-overset(O)overset(P)(C ) -overset(C_(2)H_(5))overset(|)(C ) H -C_(2)H_(5)) underset((IV))(C_(2)H_(5)-overset(CH_(3))overset(|)(C)H-C_(2)H_(5))

The following carbocation rearranges to CH_(2)=underset(CH_(3))underset(|)C-overset(CH_(3))overset(|)C-overset(o+)CH-overset(CH_(3))overset(|)(CH)-CH_(3)

Following is an example of CH_(2)=CH-overset(O)overset(||)CHharroverset(o+)CH_(2)-CH=overset(O^(-))overset("| ")C-Hharr.^(-)CH_(2)=CH-overset(O^(-))overset("| ")underset(o+)"C "-H

The number of tertiary carbon atoms in the following^ structure is CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C )-CH_(2)-overset(CH_(3))overset(|)(C )H-CH_(3)

Which H atom in the following ester is most acidic ? overset(1)(CH_(3))-overset(2)(CH_(2))-overset(O)overset(||)(C)-overset(3)(CH_(2))-overset(O)overset(||)(C)-O-overset(4)(CH_(2))overset(5)(CH_(3))

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