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CH(3)-underset(CH(3))underset(|)overset(...

`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH=CH-CH_(3)overset(H-Cl)(to)` ?

A

`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(2)-underset(Cl)underset(|)(CH)-CH_(3)`

B

`CH_(3)-underset(CH_(3))underset(|)overset(Cl)overset(|)C-CH-underset(CH_(3))underset(|)(CH_(2))-CH_(3)`

C

`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-underset(Cl)underset(|)CH=CH_(2)-CH_(3)`

D

`CH_(3)-underset(CH_(3))underset(|)overset(Cl)overset(|)C-CH_(2)-underset(CH_(3))underset(|)(CH)-CH_(3)`

Text Solution

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The correct Answer is:
To solve the question regarding the reaction of the compound with HCl, we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactant Structure**: The reactant is given as CH₃-CH(CH₃)-C(CH₃)=CH-CH₃. This structure can be broken down as follows: - A central carbon (C) bonded to two methyl groups (CH₃). - A double bond (C=C) with another carbon (C) that is also bonded to a methyl group (CH₃). 2. **Ionization of HCl**: When HCl is introduced, it ionizes into H⁺ and Cl⁻. The H⁺ ion can add to the double bond, leading to the formation of a carbocation. 3. **Formation of Carbocations**: The H⁺ can attach to either carbon of the double bond: - If H⁺ adds to the carbon with the methyl group (C1), we get a secondary carbocation. - If H⁺ adds to the other carbon (C2), we also get a secondary carbocation. Both carbocations are 2° (secondary) carbocations. 4. **Stability of Carbocations**: To determine which carbocation is more stable, we analyze hyperconjugation: - The first carbocation (C1) has more hyperconjugation structures due to the presence of adjacent methyl groups. - The second carbocation (C2) has fewer hyperconjugation structures. 5. **Select the More Stable Carbocation**: The carbocation with more hyperconjugation (C1) is more stable. Therefore, this is the one that will form. 6. **Nucleophilic Attack by Cl⁻**: The Cl⁻ ion will attack the more stable carbocation (C1), leading to the formation of the product. 7. **Write the Product Structure**: The final product after the nucleophilic attack will be: - CH₃-CH(CH₃)-C(CH₃)-CH₂-CHCl (where Cl is attached to the carbon that was originally part of the double bond). 8. **Identify the Correct Option**: Compare the product structure with the provided options. The correct answer matches with the first option. ### Final Answer: The product formed from the reaction is CH₃-CH(CH₃)-C(CH₃)-CH₂-CHCl. ---
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