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Benzene + Acetylchloride overset(AlCl(3)...

Benzene + Acetylchloride `overset(AlCl_(3))(to)` product Name of the above
reaction is

A

Wurtz fittig reaction

B

Gattermann reaction

C

Friedel Craft reaction

D

Shotten baumann reaction

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The correct Answer is:
To solve the question regarding the reaction of benzene with acetyl chloride in the presence of AlCl3, we can follow these steps: ### Step 1: Identify the Reactants - The reactants in this reaction are benzene (C6H6) and acetyl chloride (CH3COCl). ### Step 2: Understand the Role of AlCl3 - Aluminum chloride (AlCl3) acts as a Lewis acid catalyst. It helps in generating the electrophile from acetyl chloride. ### Step 3: Formation of the Electrophile - When acetyl chloride reacts with AlCl3, it forms an acylium ion (CH3C^+=O). This ion is the active electrophile that will react with benzene. ### Step 4: Electrophilic Aromatic Substitution - The acylium ion attacks the benzene ring, leading to the formation of a resonance-stabilized carbocation intermediate. This step is characteristic of electrophilic aromatic substitution reactions. ### Step 5: Deprotonation - The carbocation intermediate loses a proton (H+) to restore the aromaticity of the benzene ring, resulting in the formation of acetophenone (C6H5COCH3). ### Step 6: Identify the By-products - The by-products of this reaction are HCl and AlCl4^-. ### Step 7: Name the Reaction - The overall reaction is known as Friedel-Crafts acylation, which is a specific type of Friedel-Crafts reaction involving the introduction of an acyl group into an aromatic ring. ### Final Answer The name of the reaction is **Friedel-Crafts acylation**. ---
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  3. Benzene + Acetylchloride overset(AlCl(3))(to) product Name of the abov...

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  10. Iodination of methane can be carried out in presence of -

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  11. Which of the following can be oxidised to alcohol by KMnO(4) :-

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  13. CH(4)+H(2)Ooverset(Ni)underset(1273K)(to)'P' Product 'P' is -

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