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Major product of the following reaction ...

Major product of the following reaction
`CH_(3)-CH_(2)-Broverset(KCN)tounderset(H_(2)O)overset(overline(O)H)tounderset(Delta)overset(PCl_(5))to` product

A

`CH_(3)-CH_(2)-Cl`

B

`H_(3)C-CH_(2)-underset(O)underset(||)(C)-Cl`

C

`CH_(3)-CH_(2)-CN`

D

`CH_(3)-underset(O)underset(||)(C)-NH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the major product of the given reaction sequence, we will break down the steps involved in the reaction of ethyl bromide with KCN, followed by the treatment with OH- and H2O, and finally with PCl5 under heating. ### Step-by-Step Solution: 1. **Identify the Reactants**: The starting compound is ethyl bromide (CH3CH2Br). 2. **Reaction with KCN**: Ethyl bromide reacts with potassium cyanide (KCN). The cyanide ion (CN-) acts as a nucleophile and attacks the carbon atom bonded to the bromine atom, leading to the substitution of bromine with the cyanide group. - **Reaction**: \[ CH3CH2Br + KCN \rightarrow CH3CH2CN + KBr \] - **Product**: Ethyl cyanide (CH3CH2CN). 3. **Hydrolysis with OH- and H2O**: The ethyl cyanide then undergoes hydrolysis in the presence of hydroxide ions (OH-) and water (H2O). This process converts the nitrile (CN) group into a carboxylic acid, which can further be converted into an alcohol. - **Reaction**: \[ CH3CH2CN + H2O + OH^- \rightarrow CH3CH2COO^- + OH^- \rightarrow CH3CH2OH + CN^- \] - **Product**: Ethanol (CH3CH2OH). 4. **Reaction with PCl5**: The final step involves treating the alcohol (ethanol) with phosphorus pentachloride (PCl5) under heating. This reaction converts the alcohol into an alkyl chloride. - **Reaction**: \[ CH3CH2OH + PCl5 \rightarrow CH3CH2Cl + POCl3 + HCl \] - **Product**: Ethyl chloride (CH3CH2Cl). 5. **Final Product**: The major product of the entire reaction sequence is ethyl chloride (chloroethane). ### Conclusion: The major product of the reaction sequence is **ethyl chloride (CH3CH2Cl)**. ---
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