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CH(3)-underset(O)underset(||)(C)-CH(3)+u...

`CH_(3)-underset(O)underset(||)(C)-CH_(3)+underset(("semicarbazide"))(NH_(2)-underset(O)underset(||)(C)-NH-NH_(2)overset(H^(o+))(to)`
major product is

A

`CH_(3)-underset(O)underset(||)(C)-CH=underset(NH_(2))underset(|)(C)-NH-NH_(2)`

B

`CH_(3)-underset(CH_(3))underset(|)(C)=N-NHunderset(O)underset(||)(C)-NH_(2)`

C

`CH_(3)-underset(CH_(3))underset(|)(C)=N-underset(O)underset(||)(C)-NH-NH_(2)`

D

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AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze the reaction between a ketone and semicarbazide under acidic conditions. Let's break down the steps involved in this reaction. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in the question are: - A ketone: CH₃C(=O)CH₃ (which is acetone) - Semicarbazide: NH₂C(=O)NHNH₂ 2. **Understand the Reaction Mechanism**: When a ketone reacts with semicarbazide, a condensation reaction occurs. This involves the formation of a semicarbazone. In this reaction, a water molecule (H₂O) is eliminated. 3. **Write the General Reaction**: The general reaction can be represented as: \[ \text{R}_2C=O + \text{NH}_2C(=O)NHNH_2 \xrightarrow{H^+} \text{R}_2C=N-NH-C(=O)NH_2 + H_2O \] Here, R represents the alkyl groups from the ketone. 4. **Draw the Structure of the Ketone**: The ketone (acetone) can be represented as: \[ \text{CH}_3-C(=O)-\text{CH}_3 \] 5. **Draw the Structure of Semicarbazide**: The structure of semicarbazide is: \[ \text{NH}_2-C(=O)-\text{NH}-\text{NH}_2 \] 6. **Perform the Reaction**: - The nitrogen atom from the NH₂ group of semicarbazide attacks the carbonyl carbon of the ketone. - A water molecule is eliminated, forming a double bond between the carbon and nitrogen. 7. **Final Product Structure**: The final product after the reaction will have the following structure: \[ \text{CH}_3-C(=N-NH-C(=O)-NH_2)-\text{CH}_3 \] This structure represents the semicarbazone of the ketone. 8. **Identify the Major Product**: The major product formed from this reaction is the semicarbazone, which is a stable compound. ### Conclusion: The major product of the reaction between the ketone (acetone) and semicarbazide under acidic conditions is: \[ \text{CH}_3-C(=N-NH-C(=O)-NH_2)-\text{CH}_3 \]
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