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The key feature of Bohr's spectrum of hy...

The key feature of Bohr's spectrum of hydrogen atom is the quantization of angular momentum when an electron is revolving around a proton. We will extend this to a general rotational motion to find quantized rotational energy of a diatomic molecule assuming it to be rigid.The rule to be applied is Bohr's quantization condition.
In a `CO` molecule, the distance between `C (mass = 12 a. m. u ) and O (mass = 16 a.m.u)` where `1 a.m.u = (5)/(3) xx 10^(-27) kg , `is close to

A

a.`2.4 xx 10^(-10) m`

B

b.`1.9 xx 10^(-10) m`

C

c.`1.3 xx 10^(-10) m`

D

d.`4.4 xx 10^(-11) m`

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To find the distance between the carbon (C) and oxygen (O) atoms in a CO molecule, we will use the concept of the center of mass and the moment of inertia. ### Step-by-Step Solution: 1. **Identify the Masses:** - Mass of Carbon (C), \( m_1 = 12 \, \text{amu} \) - Mass of Oxygen (O), \( m_2 = 16 \, \text{amu} \) - Convert amu to kg: \( 1 \, \text{amu} = \frac{5}{3} \times 10^{-27} \, \text{kg} \) 2. **Calculate the Center of Mass:** - The center of mass (CM) of the system can be calculated using the formula: \[ R_{CM} = \frac{m_1 r_1 + m_2 r_2}{m_1 + m_2} \] - We set the coordinate of the center of mass to be at the origin (0,0). Let \( r_1 \) be the distance from C to CM, and \( r_2 \) be the distance from O to CM. - Since \( R_{CM} = 0 \): \[ m_1 r_1 = m_2 r_2 \] - From this, we can express \( r_2 \) in terms of \( r_1 \): \[ r_2 = \frac{m_1}{m_2} r_1 \] 3. **Express Distances in Terms of Total Distance \( D \):** - The total distance \( D \) between C and O is given by: \[ D = r_1 + r_2 \] - Substituting \( r_2 \): \[ D = r_1 + \frac{m_1}{m_2} r_1 = r_1 \left(1 + \frac{m_1}{m_2}\right) \] - Thus, we can write: \[ D = r_1 \left(1 + \frac{12}{16}\right) = r_1 \left(1 + 0.75\right) = r_1 \cdot 1.75 \] 4. **Calculate the Moment of Inertia:** - The moment of inertia \( I \) for a diatomic molecule is given by: \[ I = m_1 r_1^2 + m_2 r_2^2 \] - Substitute \( r_2 \): \[ I = m_1 r_1^2 + m_2 \left(\frac{m_1}{m_2} r_1\right)^2 = m_1 r_1^2 + \frac{m_1^2}{m_2} r_1^2 \] - Factor out \( r_1^2 \): \[ I = r_1^2 \left(m_1 + \frac{m_1^2}{m_2}\right) \] 5. **Set Up the Equation for Moment of Inertia:** - Given \( I = 1.87 \times 10^{-46} \, \text{kg m}^2 \): \[ 1.87 \times 10^{-46} = r_1^2 \left(12 + \frac{12^2}{16}\right) \] - Calculate the term in parentheses: \[ 12 + \frac{144}{16} = 12 + 9 = 21 \] - Thus: \[ 1.87 \times 10^{-46} = 21 r_1^2 \] 6. **Solve for \( r_1^2 \):** - Rearranging gives: \[ r_1^2 = \frac{1.87 \times 10^{-46}}{21} \] 7. **Calculate the Distance \( D \):** - Finally, substitute \( r_1 \) back into the equation for \( D \): \[ D = 1.75 r_1 \] - After calculating \( D \), we find that it is approximately \( 1.3 \times 10^{-10} \, \text{m} \). ### Final Answer: The distance between the C and O atoms in a CO molecule is approximately \( 1.3 \times 10^{-10} \, \text{m} \). ---

To find the distance between the carbon (C) and oxygen (O) atoms in a CO molecule, we will use the concept of the center of mass and the moment of inertia. ### Step-by-Step Solution: 1. **Identify the Masses:** - Mass of Carbon (C), \( m_1 = 12 \, \text{amu} \) - Mass of Oxygen (O), \( m_2 = 16 \, \text{amu} \) - Convert amu to kg: \( 1 \, \text{amu} = \frac{5}{3} \times 10^{-27} \, \text{kg} \) ...
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The key feature of Bohr's spectrum of hydrogen atom is the quantization of angular momentum when an electron is revolving around a proton. We will extend this to a general rotational motion to find quantized rotational energy of a diatomic molecule assuming it to be rigid.The rule to be applied is Bohr's quantization condition. A diatomic molecule has moment of inertia I . By Bohr's quantization condition its rotational energy in the n^(th) level ( n = 0 is not allowed ) is

The key feature of Bohr's spectrum of hydrogen atom is the quantization of angular momentum when an electron is revolving around a proton. We will extend this to a general rotational motion to find quantized rotational energy of a diatomic molecule assuming it to be rigid.The rule to be applied is Bohr's quantization condition. A diatomic molecule has moment of inertia I . By Bohr's quantization condition its rotational energy in the n^(th) level ( n = 0 is not allowed ) is

The key feature of Bohr's spectrum of hydrogen atom is the quantization of angular momentum when an electron is revolving around a proton. We will extend this to a general rotational motion to find quantized rotational energy of a diatomic molecule assuming it to be rigid.The rule to be applied is Bohr's quantization condition. it is found that the excitation from ground to the first excited state of rotation for the CO molecule is close to (4)/(pi) xx 10^(11) Hz then the moment of inertia of CO molecule about its center of mass is close to (Take h = 2 pi xx 10^(-34) J s )

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