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Which of the following is the strongest ...

Which of the following is the strongest base:

A

B

C

D

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The correct Answer is:
To determine which of the given amines is the strongest base, we will analyze the basicity of each compound based on the availability of the lone pair of electrons on the nitrogen atom. The basicity of amines is primarily influenced by the ability of the nitrogen's lone pair to be donated, which is affected by resonance. ### Step-by-Step Solution: 1. **Identify the Compounds**: Let's assume we have four amines labeled A, B, C, and D. Each of these amines contains a nitrogen atom with a lone pair of electrons. 2. **Understand Basicity**: Basicity in amines is related to the availability of the nitrogen's lone pair for donation. The more available the lone pair, the stronger the base. 3. **Analyze Resonance**: - In compounds A, B, and C, the nitrogen's lone pair is involved in resonance with an adjacent aromatic ring (like a benzene ring). - This involvement in resonance decreases the availability of the lone pair for donation because it is partially delocalized. 4. **Identify the Exception**: - In compound D, the nitrogen's lone pair is not involved in resonance. This means that the lone pair is fully localized on the nitrogen atom and is readily available for donation. 5. **Conclusion**: - Since compound D has its lone pair available for donation and is not involved in resonance, it will be the strongest base among the given options. ### Final Answer: The strongest base among the given amines is **Option D**. ---
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ALLEN-ACIDIC STRENGTH & BASIC STRENGTH-Exercise IV
  1. The correct order of increasing basic nature for the bases NH3....

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  2. Consider the acidity of the carboxylic acids: (1) PhCOOH (2) o-NO(...

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  3. Which of the following is the strongest base:

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  4. Among the following acids, which has the lowest pK(a) value?

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  5. Amongest the following the most basic compounds is-

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  6. What is the conjugate base of OH^(-) ?

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  7. Among the following acids which has the lowest pk(a) value-

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  8. The correct order of increasing acid strength of the compounds is (a...

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  9. Which of these is the strongest base in aqueous media?

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  10. The correct order of increasing basicity of the given conjugate bases ...

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  11. The strongest acid amongst the following compounds is?

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  12. Arrange the following compounds in increasing order of acidity and giv...

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  13. In the following compounds: the order of basicity is as follows:

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  14. The most basic compound among the following is-

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  15. Most basic amine in the gas phase is :

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  16. Arrange the following compounds in order of decreasing acidity:

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  17. Conjugate base of hydrazoic acid HN(3) is :

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  18. Which among the following compounds will not give effervescence with s...

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  19. Considering the basic strength of amines in aqueous solution, which on...

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  20. Among the following oxoacids, the correct decreasing order of acid str...

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