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The most basic compound among the follow...

The most basic compound among the following is-

A

Acetanilide

B

Benzylamine

C

p-Nitro aniline

D

Aniline

Text Solution

AI Generated Solution

The correct Answer is:
To determine the most basic compound among the given options, we need to analyze the basicity of each compound based on the presence of nitrogen with a lone pair and the influence of substituents on the nitrogen atom. Here’s a step-by-step breakdown of the solution: ### Step 1: Identify the Compounds List the compounds provided in the question. For this example, let’s assume the compounds are: 1. Acetanilide 2. Benzylamine 3. Para-nitroaniline 4. Aniline ### Step 2: Understand Basicity Basicity refers to the ability of a compound to donate a lone pair of electrons. Compounds that can easily donate their lone pairs are considered stronger bases. ### Step 3: Analyze Each Compound - **Acetanilide**: - Contains a nitrogen atom with a lone pair. - The lone pair is involved in resonance with the aromatic ring and is affected by an electron-withdrawing group (the acetyl group). - This decreases its basicity. - **Benzylamine**: - Contains a nitrogen atom with a lone pair. - The lone pair is not involved in resonance and there are no electron-withdrawing groups present. - This allows it to easily donate its lone pair, making it a strong base. - **Para-nitroaniline**: - Contains a nitrogen atom with a lone pair. - The lone pair is involved in resonance with the aromatic ring. - Additionally, the nitro group (–NO2) is a strong electron-withdrawing group, which decreases the basicity. - **Aniline**: - Contains a nitrogen atom with a lone pair. - The lone pair is also involved in resonance with the aromatic ring, which reduces its availability for donation. ### Step 4: Compare Basicity Now, compare the basicity of the analyzed compounds: - Acetanilide: Low basicity due to resonance and electron-withdrawing group. - Benzylamine: High basicity due to free lone pair and absence of electron-withdrawing groups. - Para-nitroaniline: Low basicity due to resonance and strong electron-withdrawing nitro group. - Aniline: Low basicity due to resonance. ### Conclusion The most basic compound among the given options is **Benzylamine**. ### Final Answer **Benzylamine (Option B)** is the most basic compound. ---
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