Home
Class 12
CHEMISTRY
The most basic compound among the follow...

The most basic compound among the following is-

A

Acetanilide

B

Benzylamine

C

p-Nitro aniline

D

Aniline

Text Solution

AI Generated Solution

The correct Answer is:
To determine the most basic compound among the given options, we need to analyze the basicity of each compound based on the presence of nitrogen with a lone pair and the influence of substituents on the nitrogen atom. Here’s a step-by-step breakdown of the solution: ### Step 1: Identify the Compounds List the compounds provided in the question. For this example, let’s assume the compounds are: 1. Acetanilide 2. Benzylamine 3. Para-nitroaniline 4. Aniline ### Step 2: Understand Basicity Basicity refers to the ability of a compound to donate a lone pair of electrons. Compounds that can easily donate their lone pairs are considered stronger bases. ### Step 3: Analyze Each Compound - **Acetanilide**: - Contains a nitrogen atom with a lone pair. - The lone pair is involved in resonance with the aromatic ring and is affected by an electron-withdrawing group (the acetyl group). - This decreases its basicity. - **Benzylamine**: - Contains a nitrogen atom with a lone pair. - The lone pair is not involved in resonance and there are no electron-withdrawing groups present. - This allows it to easily donate its lone pair, making it a strong base. - **Para-nitroaniline**: - Contains a nitrogen atom with a lone pair. - The lone pair is involved in resonance with the aromatic ring. - Additionally, the nitro group (–NO2) is a strong electron-withdrawing group, which decreases the basicity. - **Aniline**: - Contains a nitrogen atom with a lone pair. - The lone pair is also involved in resonance with the aromatic ring, which reduces its availability for donation. ### Step 4: Compare Basicity Now, compare the basicity of the analyzed compounds: - Acetanilide: Low basicity due to resonance and electron-withdrawing group. - Benzylamine: High basicity due to free lone pair and absence of electron-withdrawing groups. - Para-nitroaniline: Low basicity due to resonance and strong electron-withdrawing nitro group. - Aniline: Low basicity due to resonance. ### Conclusion The most basic compound among the given options is **Benzylamine**. ### Final Answer **Benzylamine (Option B)** is the most basic compound. ---
Promotional Banner

Topper's Solved these Questions

  • ACIDIC STRENGTH & BASIC STRENGTH

    ALLEN|Exercise Exercise V|16 Videos
  • ACIDIC STRENGTH & BASIC STRENGTH

    ALLEN|Exercise Exercise III|14 Videos
  • CONCENTRATION TERMS

    ALLEN|Exercise Exercise Jee-Advance|3 Videos
  • AIIMS 2019

    ALLEN|Exercise CHEMISTRY|40 Videos

Similar Questions

Explore conceptually related problems

The most acidic compound among the following is

The most polar compound among the following is :

The most basic oxide among the following is

The most basic oxide among the following is

The most basic oxide among the following is

The most basic amine among the following is

Most acidic hydrogen containing compound among the following is

The most acidic oxide among the following is

The most acidic oxide among the following is

ALLEN-ACIDIC STRENGTH & BASIC STRENGTH-Exercise IV
  1. Which of these is the strongest base in aqueous media?

    Text Solution

    |

  2. The correct order of increasing basicity of the given conjugate bases ...

    Text Solution

    |

  3. The strongest acid amongst the following compounds is?

    Text Solution

    |

  4. Arrange the following compounds in increasing order of acidity and giv...

    Text Solution

    |

  5. In the following compounds: the order of basicity is as follows:

    Text Solution

    |

  6. The most basic compound among the following is-

    Text Solution

    |

  7. Most basic amine in the gas phase is :

    Text Solution

    |

  8. Arrange the following compounds in order of decreasing acidity:

    Text Solution

    |

  9. Conjugate base of hydrazoic acid HN(3) is :

    Text Solution

    |

  10. Which among the following compounds will not give effervescence with s...

    Text Solution

    |

  11. Considering the basic strength of amines in aqueous solution, which on...

    Text Solution

    |

  12. Among the following oxoacids, the correct decreasing order of acid str...

    Text Solution

    |

  13. Among the following compounds, the increasing order of their basic str...

    Text Solution

    |

  14. The increasing order of basicity of the following compounds is

    Text Solution

    |

  15. The correct decreasing order for acid strength is :

    Text Solution

    |

  16. Arrange the follwing amines in the decreasing order of basicity :

    Text Solution

    |

  17. The increasing basicity order of the following compounds is : (A) CH...

    Text Solution

    |

  18. The increasing order of the pKa values of the following compounds is:

    Text Solution

    |

  19. In the following compound, The favourable site/s for protonation ...

    Text Solution

    |

  20. The correct order for acid strength of compounds CH-=CH,CH(3)-C-=CH ...

    Text Solution

    |