Home
Class 12
CHEMISTRY
6 gm nitrogen on successive reaction wit...

6 gm nitrogen on successive reaction with different compounds gets finally converted into 30 gm [`Cr(NH_(3))_(x)Br_(2)`] value of x is [ Atomic mass of Cr = 52, Br =80]

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we need to find the value of \( x \) in the compound \( Cr(NH_3)_xBr_2 \) given that 6 grams of nitrogen is converted into 30 grams of this complex. ### Step 1: Calculate the number of moles of nitrogen The atomic mass of nitrogen (N) is 14 g/mol. Therefore, the number of moles of nitrogen in 6 grams can be calculated using the formula: \[ \text{Number of moles of N} = \frac{\text{mass}}{\text{molar mass}} = \frac{6 \, \text{g}}{14 \, \text{g/mol}} = \frac{3}{7} \, \text{mol} \] ### Step 2: Write the expression for the number of moles of the complex The complex is given as \( Cr(NH_3)_xBr_2 \). The molar mass of the complex can be expressed as: \[ \text{Molar mass of } Cr(NH_3)_xBr_2 = 52 + 17x + 80 \times 2 = 52 + 17x + 160 = 212 + 17x \, \text{g/mol} \] ### Step 3: Calculate the number of moles of the complex The number of moles of the complex can be calculated using the total mass of the complex: \[ \text{Number of moles of complex} = \frac{\text{mass}}{\text{molar mass}} = \frac{30 \, \text{g}}{212 + 17x \, \text{g/mol}} \] ### Step 4: Set up the equation relating moles of nitrogen and moles of the complex From the stoichiometry of the reaction, we can relate the moles of nitrogen to the moles of the complex: \[ \frac{3}{7} \cdot \frac{1}{x} = \frac{30}{212 + 17x} \] ### Step 5: Cross-multiply to solve for \( x \) Cross-multiplying gives us: \[ 3(212 + 17x) = 30 \cdot 7x \] Expanding both sides: \[ 636 + 51x = 210x \] ### Step 6: Rearranging the equation Rearranging the equation to isolate \( x \): \[ 636 = 210x - 51x \] \[ 636 = 159x \] ### Step 7: Solve for \( x \) Now, divide both sides by 159: \[ x = \frac{636}{159} = 4 \] ### Conclusion The value of \( x \) is 4. Therefore, the final formula for the complex is \( Cr(NH_3)_4Br_2 \). ---
Promotional Banner

Topper's Solved these Questions

Similar Questions

Explore conceptually related problems

Cr in [Cr(NH_3)_6] Br_3 has number of unpaired electron :

How many minutes will it take to plate out 5.2g of Cr from a Cr_2(SO_4)_3 solution using a current of 9.65 A ? (Atomic mass:Cr=52.0)

Complex A has a composition of H_(12) O_6 Cl_3 Cr . If the complex on treatment with conc. H_2 SO_4 loses 13.5 % of its original mass, the correct molecular formula of A is : [Given : atomic mass of Cr=52 amu and Cl= 35 amu]

Name of following coordinatin entities and describe their structures : (i) [Fe(CN)_(6)]^(4-) (ii) [Cr(NH_(3))_(4)Cl_(2)]^(+) (iii) [Ni(CN)_(4)]^(2-) [Atomic number Fe = 26 , Cr = 24 , Ni = 28]

How much gm of bromine reacts with 3.15 gm of butane -2-ene (Atomic mass of bromine =80 )

Consider the following reaction and based on the reaction answer the question that follow: (NH_4)_2 Cr_2 O_7 to N_2 (g)+ 4H_2 O (g) + Cr_2 O_3 Calculate : The mass in grams of Cr_2 O_3 formed at the same time [Atomic massess : H= 1 , Cr = 52 , N= 14]

Z_(2) undergo disproportion in an alkaline medium into a mixture of Z^(-) and ZO_(3)^(-) . Equivalent mass of Z_(2) in the reaction is: [given that atomic mass of Z is 80 gm/mol]

An organic compound with vapour density = 94 contains C=12.67%, H = 2.13%, and Br = 85-11%. Find the molecular formula. [Atomic mass: C = 12, H = 1, Br = 80]

An organic compound with vapour density 94 contains C = 12.67%, H = 2.13% and Br = 85.20%. Find the molecular formula. (Atomic mass: C = 12, H = 1, Br = 80)

The density of chormium is 7.2"g cm"^(-3) . If the unit cell is a cube edge length of 298 pm, determine the type of the unit cell. (Atomic mass of Cr = 52 amu)

ALLEN-MOLE CONCEPT-S-I (Problems Related with Different Types of Atomic Masses & Basic Concept of Mole)
  1. If a sample of pure SO(4) gas is heated to 600^(@)C, it dissociates in...

    Text Solution

    |

  2. When silent electric discharge is passed through O(2) gas, it converts...

    Text Solution

    |

  3. When acethlene (C(2)H(2)) gas is passed through red hot iron tube, it ...

    Text Solution

    |

  4. Br(2)(l) reacts with Cl(2) (g) to form BrCl(3) ,simultaneously .How ma...

    Text Solution

    |

  5. When 80 gm CH(4) is burnt completely , CO and CO(2) gases are formed i...

    Text Solution

    |

  6. Consider the following reaction sequence: S(8)(s) + 8O(2)(g) to 8SO(...

    Text Solution

    |

  7. Potassium superoxide ,KO(2), is utilised in closed system breathing ap...

    Text Solution

    |

  8. In a determination of P an aqueous solution of NaH(2)PO(4) is treated ...

    Text Solution

    |

  9. 6 gm nitrogen on successive reaction with different compounds gets fin...

    Text Solution

    |

  10. A 5.00 gm sample of a natural gas, consisting of methane CH(4), and et...

    Text Solution

    |

  11. All carbon atom present in KH(3)(C(2)O(4) )(2).2H(2)O weighing 254 gm ...

    Text Solution

    |

  12. Haemoglobin contains 0.25% iron by weight. The molecular weight of hae...

    Text Solution

    |

  13. 1.6 g of an organic compound containing sulphur,produces 0.233 g of Ba...

    Text Solution

    |

  14. 90g of silver coin was dissolved in strong nitric acid, and excess of ...

    Text Solution

    |

  15. When 2.0 gm of organic compound is burnt completely , 150 ml N(2) gas ...

    Text Solution

    |

  16. A polystryrene, having formula Br(3) C(6) H(2) (C(8) H(8))(n), was per...

    Text Solution

    |

  17. A moth repellent has the composition 49% C, 2.7%H and 48.3% Cl. Its mo...

    Text Solution

    |

  18. 0.5 g of NaOH is required by 0.4 gm of a polybasic acid H(n)A (Molecul...

    Text Solution

    |

  19. The empirical formula of a compounds is CH(2)O. 0.25 mole of this comp...

    Text Solution

    |

  20. A compound has 62 % carbon, 10.4% hydrogen and 27.5% oxygen. If molar ...

    Text Solution

    |