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A' reacts by following two parallel reac...

A' reacts by following two parallel reactions to give B& C If half of 'A' goes into reaction I and other half goes to reaction-II . Then , select the correct statement(s)
`A+N overset(I) to B +L`
`A+N overset(II)to (1)/(2) B+(1)/(2)(C)+L`

A

B will be always greater than C

B

If 2 mole of C are formed then total 2 mole of B are also formed

C

If 2 mole of C are formed then total 4 mole of B are also formed

D

If 2 mole of C are formed then total 6 mole of B are also formed

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the two parallel reactions involving the substance A. Let's break down the steps systematically. ### Step 1: Write the Reactions We have two reactions: 1. Reaction I: \( A + N \rightarrow B + L \) 2. Reaction II: \( A + N \rightarrow \frac{1}{2}B + \frac{1}{2}C + L \) ### Step 2: Define the Amount of A Let’s assume we start with \( x \) moles of A. According to the problem, half of A goes into each reaction: - Amount of A in Reaction I: \( \frac{x}{2} \) - Amount of A in Reaction II: \( \frac{x}{2} \) ### Step 3: Determine the Products from Each Reaction Now, we will calculate the amount of B and C produced from each reaction: - From Reaction I: - Since \( \frac{x}{2} \) moles of A react, the amount of B produced will be \( \frac{x}{2} \) moles (assuming a 1:1 stoichiometry). - From Reaction II: - Since \( \frac{x}{2} \) moles of A react, the amount of B produced will be \( \frac{1}{4}x \) moles (because only half of B is produced). - The amount of C produced will be \( \frac{1}{4}x \) moles (because only half of C is produced). ### Step 4: Total Moles of B and C Now, we can calculate the total moles of B and C produced: - Total moles of B: \[ B_{total} = B_{I} + B_{II} = \frac{x}{2} + \frac{1}{4}x = \frac{2}{4}x + \frac{1}{4}x = \frac{3}{4}x \] - Total moles of C: \[ C_{total} = C_{II} = \frac{1}{4}x \] ### Step 5: Compare the Amounts of B and C Now we can compare the total moles of B and C: - Since \( \frac{3}{4}x > \frac{1}{4}x \), it is clear that the total moles of B are always greater than the total moles of C. ### Step 6: Analyze the Given Statements 1. **Statement 1**: B is always greater than C. This is **correct**. 2. **Statement 2**: If 2 moles of C are formed, then total moles of B are... - If \( C = 2 \) moles, then: \[ \frac{1}{4}x = 2 \implies x = 8 \] - Therefore, total moles of B: \[ B_{total} = \frac{3}{4}x = \frac{3}{4} \times 8 = 6 \text{ moles} \] - This statement is also **correct**. ### Conclusion The correct statements are: - B is always greater than C. - If 2 moles of C are formed, then total moles of B are 6.
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