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Acetylene when treated with dilute HCl a...

Acetylene when treated with dilute `HCl` at `60^(@)C(333K)` in presence of `HgCl_(2)` produces-

A

Methyl chloride

B

Vinyl chloride

C

Acetaldehyde

D

Formaidelhyde

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The correct Answer is:
To solve the problem of what acetylene produces when treated with dilute HCl at 60°C (333 K) in the presence of HgCl2, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactant in this case is acetylene, which has the chemical formula \( \text{HC} \equiv \text{CH} \). 2. **Understand the Reaction Conditions**: The reaction occurs in the presence of dilute hydrochloric acid (HCl) and mercuric chloride (HgCl2) at a temperature of 60°C (333 K). This indicates that we are likely dealing with an electrophilic addition reaction. 3. **Write the Reaction**: When acetylene reacts with dilute HCl in the presence of HgCl2, the reaction proceeds via the formation of a vinyl cation. The reaction can be represented as follows: \[ \text{HC} \equiv \text{CH} + \text{HCl} \xrightarrow{\text{HgCl}_2} \text{CH}_2=\text{CHCl} \] Here, the acetylene adds HCl across the triple bond. 4. **Identify the Product**: The product formed is vinyl chloride, which has the chemical structure \( \text{CH}_2=\text{CHCl} \). This is a compound where a chlorine atom is added to the double bond of the ethylene structure. 5. **Select the Correct Option**: From the options given, we need to identify which one corresponds to the product vinyl chloride. The options are: - A) Methyl chloride - B) Vinyl chloride - C) Acetaldehyde - D) Formaldehyde The correct answer is **B) Vinyl chloride**. ### Final Answer: The product formed when acetylene is treated with dilute HCl at 60°C in the presence of HgCl2 is **vinyl chloride**. ---

To solve the problem of what acetylene produces when treated with dilute HCl at 60°C (333 K) in the presence of HgCl2, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactant in this case is acetylene, which has the chemical formula \( \text{HC} \equiv \text{CH} \). 2. **Understand the Reaction Conditions**: The reaction occurs in the presence of dilute hydrochloric acid (HCl) and mercuric chloride (HgCl2) at a temperature of 60°C (333 K). This indicates that we are likely dealing with an electrophilic addition reaction. ...
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ALLEN-ALKENE, ALKANE & ALKYNE -EXCERSISE-3
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  2. True or False

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  3. Heating of beta-hydroxy acid gives lactones.

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  4. Hunsdiecker reaction involve free radical in intermediate steps.

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  5. Benzoic acid is stronger than methanoic acid but weaker than ethanoic ...

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  6. Acid halides are more reactive than acid amides towards the hydrolysis...

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  7. What happens when sodium benzoate is heated with soda lime?

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  8. pK(a) and K(a) of an acid are connected by the relation.......

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  9. Fill in the blank by choosing the appropriate word/words from those gi...

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  10. Hell-Volhard-Zelinsky reaction involves the replacement of an ...........

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  11. Carboxylic acids may be prepared by the reaction of Grigrand reagents ...

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  12. Statement-I: Unlike the gtC=O group of aldehydes and ketones, the C=O ...

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  13. Statement-I: CH(3)COCH(2)COOC(2)H(5) will give iodoform test. Becau...

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  14. Statement-1: Acetic acid does not undergo haloform test. and State...

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  15. Statement-I: Benzoic acid on nitration will give m- nitro benzoic ac...

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  16. Statement-I: Acyl halide are more reactive than acid substance amide t...

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  17. Amides undergo hydrolysis to yield carboxylic acid plus amine on heati...

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  18. Amides undergo hydrolysis to yield carboxylic acid plus amine on heati...

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  19. Acid halides are more reactive than acid amides towards the hydrolysis...

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  20. When is treated with two equivalent of methyl magnesium iodide a...

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  21. Ester gives nucleophilic addition reaction followed by elimination rea...

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