Home
Class 12
CHEMISTRY
Alkaline KMnO(4). Oxidizes acetylene to ...

Alkaline `KMnO_(4)`. Oxidizes acetylene to -

A

Acetic acid

B

Glyoxal

C

Oxalic acid

D

Ethylene glycol

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the oxidation of acetylene by alkaline KMnO₄, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - Acetylene is the simplest alkyne, with the chemical formula C₂H₂ (or CH≡CH). - Alkaline KMnO₄ is a strong oxidizing agent used for oxidation reactions. 2. **Understand the Reaction**: - Alkaline KMnO₄ oxidizes alkynes and alkenes to form diols (compounds with two hydroxyl groups, -OH). - The reaction involves the addition of hydroxyl groups across the double or triple bond. 3. **Write the Reaction**: - The reaction of acetylene (C₂H₂) with alkaline KMnO₄ can be represented as: \[ \text{C}_2\text{H}_2 + \text{KMnO}_4 \xrightarrow{\text{KOH}} \text{C}_2\text{H}_6\text{O}_2 \] - Here, C₂H₆O₂ represents ethylene glycol (or ethane-1,2-diol). 4. **Identify the Product**: - The product formed from the reaction is ethylene glycol (C₂H₆O₂), which is also known as ethane-1,2-diol. 5. **Reduction of KMnO₄**: - During this reaction, KMnO₄ is reduced to manganese dioxide (MnO₂). 6. **Conclusion**: - Therefore, the final answer to the question is that alkaline KMnO₄ oxidizes acetylene to form ethylene glycol (C₂H₆O₂). ### Final Answer: Alkaline KMnO₄ oxidizes acetylene to ethylene glycol (C₂H₆O₂). ---

To solve the question regarding the oxidation of acetylene by alkaline KMnO₄, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - Acetylene is the simplest alkyne, with the chemical formula C₂H₂ (or CH≡CH). - Alkaline KMnO₄ is a strong oxidizing agent used for oxidation reactions. ...
Promotional Banner

Topper's Solved these Questions

  • ALKENE, ALKANE & ALKYNE

    ALLEN|Exercise EXERCISE-1|119 Videos
  • ALKENE, ALKANE & ALKYNE

    ALLEN|Exercise EXERCISE-2|103 Videos
  • AIIMS 2019

    ALLEN|Exercise CHEMISTRY|40 Videos
  • ALKYL AND ARYL HALIDE

    ALLEN|Exercise EXERCISE-05 (B)|35 Videos

Similar Questions

Explore conceptually related problems

Alkaline KMnO_(4) used for the detection of unsaturation in organic compounds is called.................

(a) Give the equations of the following reactions: (i) Oxidation of propan-1-ol with alkaline KMnO_(4) solution. (ii) Propene to propan-2-ol (iii) Benzyl chloride to benzyl alcohol (iv) Ethylmagnesium chloride to propan-1-ol. (b) Write the reactions and their conditions only for the commercial preparation of phenol from cumene.

How many isomers 'X' of C_(8)H_(10) given only aromatic dicarboxylic acid when react with hot alkaline KMNO_(4) . How many isomers 'Y' of C_(4)H_(8) give CO_(2) when reacts withh hot alkaline KMnO_(4) . Find the value of X+Y ?

Assertion : In the presence of alkaline KMnO_(4) 4-methylacetophenone is oxidised to benzoic acid. Reason : Keto group is oxidised to -COOH group.

KMnO_(4) acts as on oxidising agent in alkaline medium. When alkaline KMnO_(4) is treated with KI , iodide ion is oxidised to …………….

KMnO_(4) acts as on oxidising agent in alkaline medium. When alkaline KMnO_(4) is treated with KI , iodide ion is oxidised to …………….

Assertion : cis -2- butene gives meso-2, 3-butanediol with dilute alkaline KMnO_(4) solution. Reason : Dilute alkaline KMnO_(4) solution gives trans addition with alkenes.

But-2-ene on reaction with alkaline KMnO_(4) at elevated temperature followed by acidification will give :

Give the equations of the following reactions: i. Oxidation of propan-1-ol with alkaline KMnO_(4) solution. ii. Bromine in CS_(2) with phenol. iii. Dilute HNO_(3) with phenol. iv. Treating phenol with chloroform in the presence of aqueous NaOH.

Which of the following on oxidation with alkaline KMnO_(4) follwed by acidification with dil. HCl gives terephthalic acid?

ALLEN-ALKENE, ALKANE & ALKYNE -EXCERSISE-3
  1. Alkaline KMnO(4). Oxidizes acetylene to -

    Text Solution

    |

  2. True or False

    Text Solution

    |

  3. Heating of beta-hydroxy acid gives lactones.

    Text Solution

    |

  4. Hunsdiecker reaction involve free radical in intermediate steps.

    Text Solution

    |

  5. Benzoic acid is stronger than methanoic acid but weaker than ethanoic ...

    Text Solution

    |

  6. Acid halides are more reactive than acid amides towards the hydrolysis...

    Text Solution

    |

  7. What happens when sodium benzoate is heated with soda lime?

    Text Solution

    |

  8. pK(a) and K(a) of an acid are connected by the relation.......

    Text Solution

    |

  9. Fill in the blank by choosing the appropriate word/words from those gi...

    Text Solution

    |

  10. Hell-Volhard-Zelinsky reaction involves the replacement of an ...........

    Text Solution

    |

  11. Carboxylic acids may be prepared by the reaction of Grigrand reagents ...

    Text Solution

    |

  12. Statement-I: Unlike the gtC=O group of aldehydes and ketones, the C=O ...

    Text Solution

    |

  13. Statement-I: CH(3)COCH(2)COOC(2)H(5) will give iodoform test. Becau...

    Text Solution

    |

  14. Statement-1: Acetic acid does not undergo haloform test. and State...

    Text Solution

    |

  15. Statement-I: Benzoic acid on nitration will give m- nitro benzoic ac...

    Text Solution

    |

  16. Statement-I: Acyl halide are more reactive than acid substance amide t...

    Text Solution

    |

  17. Amides undergo hydrolysis to yield carboxylic acid plus amine on heati...

    Text Solution

    |

  18. Amides undergo hydrolysis to yield carboxylic acid plus amine on heati...

    Text Solution

    |

  19. Acid halides are more reactive than acid amides towards the hydrolysis...

    Text Solution

    |

  20. When is treated with two equivalent of methyl magnesium iodide a...

    Text Solution

    |

  21. Ester gives nucleophilic addition reaction followed by elimination rea...

    Text Solution

    |