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The addition of HCl to 1-phenylpropene g...

The addition of `HCl` to `1-`phenylpropene gives-

A

`(a)C_(6)H_(5)CHClCH_(2)CH_(6)`

B

(b)`C_(6)H_(5)CH_(2)CHClCH_(2)`

C

(c)`C_(6)H_(5)CH_(2)CH_(2)CH_(2)Cl`

D

(d)`C_(6)H_(5)CH(CH_(3))CH_(2)Cl`

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The correct Answer is:
To solve the question regarding the addition of HCl to 1-phenylpropene, we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of 1-Phenylpropene**: - 1-Phenylpropene consists of a propene chain (C3H6) with a phenyl group (C6H5) attached to the first carbon. The structure can be represented as: \[ \text{C}_6\text{H}_5-\text{C}=\text{C}(\text{H})-\text{CH}_3 \] 2. **Understand the Reaction with HCl**: - When HCl is added to alkenes, it dissociates into H⁺ and Cl⁻ ions. The H⁺ ion will add to one of the carbons in the double bond, while the Cl⁻ ion will add to the other carbon. 3. **Formation of Carbocations**: - The addition of H⁺ to the double bond can lead to the formation of two possible carbocations: - **Intermediate 1**: H⁺ adds to the terminal carbon (C2), leading to a carbocation on C1. - **Intermediate 2**: H⁺ adds to the internal carbon (C1), leading to a carbocation on C2. - The structures of the intermediates can be represented as: - **Intermediate 1**: \[ \text{C}_6\text{H}_5-\text{C}^+(\text{H})-\text{CH}_2-\text{CH}_3 \] - **Intermediate 2**: \[ \text{C}_6\text{H}_5-\text{C}(\text{H})-\text{C}^+(\text{Cl})-\text{H} \] 4. **Stability of Carbocations**: - The stability of the carbocations is crucial. The carbocation that is resonance-stabilized by the phenyl group will be more stable. Therefore, the carbocation formed in Intermediate 1 is more stable due to resonance with the benzene ring. 5. **Formation of Products**: - From Intermediate 1, the Cl⁻ will add to the more stable carbocation, leading to the final product: \[ \text{C}_6\text{H}_5-\text{C}(\text{Cl})-\text{CH}_2-\text{CH}_3 \] - This product can be named as 1-chloro-1-phenylpropane. 6. **Final Answer**: - The product formed from the addition of HCl to 1-phenylpropene is: \[ \text{C}_6\text{H}_5-\text{C}(\text{Cl})-\text{CH}_2-\text{CH}_3 \quad \text{(1-chloro-1-phenylpropane)} \]
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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-1
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  2. An optically active hydrocarbon X has molecular formula C(6)H(12). X ...

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  3. The addition of HCl to 1-phenylpropene gives-

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  5. The ease of formation of free radicals follows the order -

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  6. Which of the following has the smallest heat of hydrogenation per mole...

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  7. The intermediate during the addition of HCl to propene n presence of p...

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  8. The order of stability of the alkenes underset(I)(R(2)C=CR(2)') unde...

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  10. The correct order of reactivity towards the electrophillic substituion...

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  11. Which of the following order is correct for the decreasing reactivity ...

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  12. Electrophile overset(o+)NO(2) attacks the following : In which ca...

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  13. The most deactivating group for electrophilic substitution reaction in...

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  14. Which of the following is the most reactive towards ring nitration ?

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  15. The order decreasing reactivity towards an electrophilic reagent, for ...

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  16. Increasing order of the following for electrophilic substitution react...

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  17. Among the compounds the order of decreasing reactivity towards electro...

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  18. Choose the most reactive among the following compound :

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  19. Write the structures of possible isomers of dichlorobenzene.

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  20. The major product form by the monobromination of phenyl benzoate is

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